Bonding and structure trends of thiosemicarbazone derivatives of metals—an overview

TS Lobana, R Sharma, G Bawa, S Khanna - Coordination Chemistry …, 2009 - Elsevier
This review describes the coordination chemistry of thiosemicarbazones and covers all the
metals for which complexes are reported. The coordination compounds of d-block, p-block …

Metal complexes of thiosemicarbazones for imaging and therapy

JR Dilworth, R Hueting - Inorganica Chimica Acta, 2012 - Elsevier
This review gives an account of the coordination chemistry of thiosemicarbazone ligands
with three (tridentate) or four (tetradentate) potential donor atoms. The syntheses and …

l-Isoleucine-Schiff Base Copper(II) Coordination Polymers: Crystal Structure, Spectroscopic, Hirshfeld Surface, and DFT Analyses

IF Chavez-Urias, LE López-González… - ACS …, 2023 - ACS Publications
A new copper (II) coordination polymer was synthesized from the l-isoleucine-Schiff base
and characterized by elemental analysis, Fourier transform infrared (FT-IR) spectroscopy …

Structural, antimicrobial and spectral studies of copper (II) complexes of 2-benzoylpyridine N (4)-phenyl thiosemicarbazone

M Joseph, M Kuriakose, MRP Kurup, E Suresh… - Polyhedron, 2006 - Elsevier
Reaction of 2-benzoylpyridine N (4)-phenyl thiosemicarbazone (HL) with a variety of copper
salts yielded a series of copper (II) complexes of the type [CuLX] where X= Cl (1), Br (2) …

Iron chelators of the dipyridylketone thiosemicarbazone class: precomplexation and transmetalation effects on anticancer activity

PV Bernhardt, PC Sharpe, M Islam… - Journal of medicinal …, 2009 - ACS Publications
We previously reported a series of di-2-pyridylketone thiosemicarbazone (H DpT) chelators
that showed marked and selective antitumor activity (Whitnall, M.; et al. Proc. Natl. Acad. Sci …

Copper (II) complexes of N (4)-substituted thiosemicarbazones derived from pyridine-2-carbaldehyde: Crystal structure of a binuclear complex

PF Rapheal, E Manoj, MRP Kurup - Polyhedron, 2007 - Elsevier
Ten copper (II) complexes {[CuL1Cl](1),[CuL1NO3] 2 (2),[CuL1N3] 2· 2/3H2O (3),[CuL1] 2
(ClO4) 2· 2H2O (4),[CuL2Cl] 2 (5),[CuL2N3](6),[Cu (HL2) SO4] 2· 4H2O (7),[Cu (HL2) …

Medicinal utility of thiosemicarbazones with special reference to mixed ligand and mixed metal complexes: A Review

T Khan, S Raza, AJ Lawrence - Russian Journal of Coordination …, 2022 - Springer
Thiosemicarbazone complexes possess structural diversity and variable bonding patterns
and potential biological implications and ion sensing abilities. The ability of the transition …

Spectroscopic and theoretical studies on Cr (III), Mn (II) and Cu (II) complexes of hydrazone derived from picolinic hydrazide and O‐vanillin and evaluation of …

GAA Al‐Hazmi, KS Abou‐Melha… - Applied …, 2020 - Wiley Online Library
Trivalent Cr (III) and divalent of both Mn (II) and Cu (II) complexes containing hydrazone
ligands derived from the condensation of picolinohydrazide with O‐vanillin were …

5-Methoxyisatin N (4)-Pyrrolidinyl Thiosemicarbazone (MeOIstPyrd) Restores Mutant p53 and Inhibits the Growth of Skin Cancer Cells, In Vitro

N Shahi, PN Yadav, U Chaudhary, M Saad… - ACS …, 2023 - ACS Publications
A series of novel thiosemicarbazone derivatives containing 5-methoxy isatin were designed
and synthesized with modification on N (4) position. Derivatives considering structure …

Synthesis of four binuclear copper (II) complexes: Structure, anticancer properties and anticancer mechanism

J Qi, S Liang, Y Gou, Z Zhang, Z Zhou, F Yang… - European Journal of …, 2015 - Elsevier
Copper (Cu) compounds are a promising candidate for next generation metal anticancer
drugs and have been extensively studied. Therefore, four binuclear copper (II) compounds …