This Minireview highlights advances in the Suzuki–Miyaura cross‐coupling of secondary
boron reagents for the creation of C C bonds with control of stereochemistry. It also …

Transition‐metal‐catalyzed tandem reactions have become a mainstay in organic chemistry
owing to their high atom‐and step‐economies. Metal‐migration‐based tandem reactions …

Synthesis of free‐standing two‐dimensional (2D) conjugated covalent organic framework
(COF) films linked by C− C bonds is highly desirable. Now a very simple and mild strategy …

The stereospecific cross-coupling of secondary boronic esters with sp2 electrophiles (Suzuki–
Miyaura reaction) is a long-standing problem in synthesis, but progress has been achieved …

Although nanoparticles are widely used as catalysts, little is known about their potential
ability to trigger privileged transformations as compared to homogeneous molecular or bulk …

The outcome of the Suzuki–Miyaura cross‐coupling for the direct competition reaction
between two boronic acids was evaluated under routine synthesis conditions. The reaction …

Batrachotoxin is an extremely potent cardio‐and neurotoxic steroidal alkaloid found in
certain species of frogs, birds, and beetles. The steroidal 6/6/6/5‐membered carbocycle …

Preparing conjugated polymer films via interfacial Suzuki polymerization is a promising
method for obtaining desirable electrochromic materials with desired structures. Here, a …

Abstract Suzuki, Negishi, and Kumada couplings are some of the most important reactions
for the formation of skeletal C− C linkages. Their widespread use to forge bonds between …

An efficient synthesis of biaryls through a gold‐catalyzed oxidative cross‐coupling of arenes
with strong electron‐deprived aryl boronates is presented herein. Regio‐and chemocontrol …