Toward the design and construction of supramolecular functional molecular materials based on metal–metal interactions

MHY Chan, VWW Yam - Journal of the American Chemical …, 2022 - ACS Publications
Supramolecular functional materials represent an emerging class of materials that have
been governed by the supramolecular chemistry of self-assembled molecules. Such high …

Modulating the chemical reactivity of gold complexes in living systems: from concept to biomedical applications

J Jiang, X Xiong, T Zou - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Over the past few decades, research on the chemistry of gold has progressed
rapidly, encompassing topics like catalysis, supramolecular chemistry, molecular …

Elucidation of the key role of Pt··· Pt interactions in the directional self-assembly of platinum (II) complexes

X Zheng, MHY Chan, AKW Chan… - Proceedings of the …, 2022 - National Acad Sciences
Here, we report the use of an amphiphilic Pt (II) complex, K [Pt {(O3SCH2CH2CH2)
2bzimpy} Cl](PtB), as a model to elucidate the key role of Pt··· Pt interactions in directing self …

Relativistic effects on the chemical bonding properties of the heavier elements and their compounds

A Das, U Das, AK Das - Coordination Chemistry Reviews, 2023 - Elsevier
It is now well established that the relativistic effects strongly influence the properties of the
heavier elements, specially the heavier elements of d-and f-block and also the heavier main …

Aggregation-enhanced emission in a red Cu (I) emitter with quantum yield> 99%

H Yang, J Zheng, M Xie, D Luo, WJ Tang… - ACS Materials …, 2022 - ACS Publications
It is a significant challenge to achieve a high photoluminescence quantum yield of Cu (I)
complexes, particularly for red Cu (I) emitters, because of their considerable reorganization …

Origins of Lewis acid acceleration in nickel-catalysed C–H, C–C and C–O bond cleavage

H Gao, L Hu, Y Hu, X Lv, YB Wu, G Lu - Catalysis Science & …, 2021 - pubs.rsc.org
The current understanding of Lewis acid effects on transition metal catalysis is generally
based on the enhanced charge transfer from metal to substrate due to the formation of Lewis …

Controlled Self‐assembly of Gold (I) Complexes by Multiple Kinetic Aggregation States with Nonlinear Optical and Waveguide Properties

Z Li, K Xiao, Q Wan, R Tang, KH Low… - Angewandte Chemie …, 2023 - Wiley Online Library
Introduction of multiple kinetic aggregation states (Aggs) into the self‐assembly pathway
could bring complexity and flexibility to the self‐assemblies, which is difficult to realize due to …

Optical Signal Modulation in Photonic Waveguiding Heteroarchitectures with Continuously Variable Visible‐To‐Near‐Infrared Emission Color

Q Wan, K Xiao, Z Li, J Yang, JT Kim, X Cui… - Advanced …, 2022 - Wiley Online Library
Photonic circuit systems based on optical waveguiding heteroarchitectures have attracted
considerable interest owing to their potential to overcome the speed limitation in electronic …

Selective coordination of coinage metals using orthogonal ligand scaffolds

VR Naina, F Krätschmer, PW Roesky - Chemical Communications, 2022 - pubs.rsc.org
Group 11 metal complexes with their ability to form metallophilic interations are widely
pursued to develop multifunctional luminescent materials. Heteronuclear coinage metal …

Structure and bonding in rhodium coordination compounds: a 103 Rh solid-state NMR and relativistic DFT study

ST Holmes, J Schönzart, AB Philips, JJ Kimball… - Chemical …, 2024 - pubs.rsc.org
This study demonstrates the application of 103Rh solid-state NMR (SSNMR) spectroscopy
to inorganic and organometallic coordination compounds, in combination with relativistic …