Toward the design and construction of supramolecular functional molecular materials based on metal–metal interactions
Supramolecular functional materials represent an emerging class of materials that have
been governed by the supramolecular chemistry of self-assembled molecules. Such high …
been governed by the supramolecular chemistry of self-assembled molecules. Such high …
Modulating the chemical reactivity of gold complexes in living systems: from concept to biomedical applications
J Jiang, X Xiong, T Zou - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Over the past few decades, research on the chemistry of gold has progressed
rapidly, encompassing topics like catalysis, supramolecular chemistry, molecular …
rapidly, encompassing topics like catalysis, supramolecular chemistry, molecular …
Elucidation of the key role of Pt··· Pt interactions in the directional self-assembly of platinum (II) complexes
Here, we report the use of an amphiphilic Pt (II) complex, K [Pt {(O3SCH2CH2CH2)
2bzimpy} Cl](PtB), as a model to elucidate the key role of Pt··· Pt interactions in directing self …
2bzimpy} Cl](PtB), as a model to elucidate the key role of Pt··· Pt interactions in directing self …
Relativistic effects on the chemical bonding properties of the heavier elements and their compounds
It is now well established that the relativistic effects strongly influence the properties of the
heavier elements, specially the heavier elements of d-and f-block and also the heavier main …
heavier elements, specially the heavier elements of d-and f-block and also the heavier main …
Aggregation-enhanced emission in a red Cu (I) emitter with quantum yield> 99%
It is a significant challenge to achieve a high photoluminescence quantum yield of Cu (I)
complexes, particularly for red Cu (I) emitters, because of their considerable reorganization …
complexes, particularly for red Cu (I) emitters, because of their considerable reorganization …
Origins of Lewis acid acceleration in nickel-catalysed C–H, C–C and C–O bond cleavage
H Gao, L Hu, Y Hu, X Lv, YB Wu, G Lu - Catalysis Science & …, 2021 - pubs.rsc.org
The current understanding of Lewis acid effects on transition metal catalysis is generally
based on the enhanced charge transfer from metal to substrate due to the formation of Lewis …
based on the enhanced charge transfer from metal to substrate due to the formation of Lewis …
Controlled Self‐assembly of Gold (I) Complexes by Multiple Kinetic Aggregation States with Nonlinear Optical and Waveguide Properties
Z Li, K Xiao, Q Wan, R Tang, KH Low… - Angewandte Chemie …, 2023 - Wiley Online Library
Introduction of multiple kinetic aggregation states (Aggs) into the self‐assembly pathway
could bring complexity and flexibility to the self‐assemblies, which is difficult to realize due to …
could bring complexity and flexibility to the self‐assemblies, which is difficult to realize due to …
Optical Signal Modulation in Photonic Waveguiding Heteroarchitectures with Continuously Variable Visible‐To‐Near‐Infrared Emission Color
Photonic circuit systems based on optical waveguiding heteroarchitectures have attracted
considerable interest owing to their potential to overcome the speed limitation in electronic …
considerable interest owing to their potential to overcome the speed limitation in electronic …
Selective coordination of coinage metals using orthogonal ligand scaffolds
Group 11 metal complexes with their ability to form metallophilic interations are widely
pursued to develop multifunctional luminescent materials. Heteronuclear coinage metal …
pursued to develop multifunctional luminescent materials. Heteronuclear coinage metal …
Structure and bonding in rhodium coordination compounds: a 103 Rh solid-state NMR and relativistic DFT study
ST Holmes, J Schönzart, AB Philips, JJ Kimball… - Chemical …, 2024 - pubs.rsc.org
This study demonstrates the application of 103Rh solid-state NMR (SSNMR) spectroscopy
to inorganic and organometallic coordination compounds, in combination with relativistic …
to inorganic and organometallic coordination compounds, in combination with relativistic …