Intrinsic Reactivity of [η5-1,3-(Me3C)2C5H3]2Th(bipy) toward Small Molecules
D Wang, Y Heng, T Li, G Zi, MD Walter - Organometallics, 2024 - ACS Publications
The reactivity of the thorium bipyridyl metallocene (Cp2 t Bu) 2Th (bipy)(1; Cp2 t Bu= η 5-1, 3-
(Me3C) 2C5H3) toward a series of small molecules was explored, and the emerging …
(Me3C) 2C5H3) toward a series of small molecules was explored, and the emerging …
Influence of 1,2,4-Tri-tert-butylcyclopentadienyl Ligand on the Reactivity of the Thorium Bipyridyl Metallocene [η5-1,2,4-(Me3C)3C5H2]2Th(bipy)
D Wang, Y Heng, T Li, W Ding, G Hou, G Zi… - Inorganic …, 2024 - ACS Publications
The thorium bipyridyl metallocene (Cp3 t Bu) 2Th (bipy)(1; Cp3 t Bu= η5-1, 2, 4-(Me3C)
3C5H2) shows a rich reactivity toward a series of small molecules. For example, complex 1 …
3C5H2) shows a rich reactivity toward a series of small molecules. For example, complex 1 …
Synthesis and Structure of [η5-1,2,4-(Me3Si)3C5H2]2Th(bipy) and Its Reactivity toward Small Molecules
S Wang, D Wang, Y Heng, T Li, W Ding, G Zi… - Inorganic …, 2024 - ACS Publications
Halide exchange of (Cp3tms) 2ThCl2 (1; Cp3tms= η5-1, 2, 4-(Me3Si) 3C5H2) with Me3SiI
furnishes (Cp3tms) 2ThI2 (2), which is then reduced with potassium graphite (KC8) in the …
furnishes (Cp3tms) 2ThI2 (2), which is then reduced with potassium graphite (KC8) in the …
Investigating Steric and Electronic Effects in the Synthesis of Square Planar 6d1 Th(III) Complexes
The factors affecting the formation and crystal structures of unusual 6d1 Th (III) square
planar aryloxide complexes, as exemplified by [Th (OArMe) 4] 1–(OArMe= OC6H2 t Bu2-2, 6 …
planar aryloxide complexes, as exemplified by [Th (OArMe) 4] 1–(OArMe= OC6H2 t Bu2-2, 6 …
Uranium Chemistry: Identifying the Next Frontiers
DMT Eralie, J Ducilon, AEV Gorden - Inorganic Chemistry, 2024 - ACS Publications
While uranium is the most extensively studied actinide in terms of chemical properties, there
remains much to be explored about its fundamental chemistry. Organometallic and …
remains much to be explored about its fundamental chemistry. Organometallic and …
Bis (acyl) phosphide Complexes of U (III)/U (IV): A Case of a Hidden Redox-Active Ligand
D Samuvel Michael, G Schreckenbach - Inorganic Chemistry, 2024 - ACS Publications
The recently reported tris (bis (2, 4, 6-triisopropylbenzoyl)-phosphide) uranium (UIII
(trippBAP) 3, 2) complex (Inorg. Chem. 2022, 61 (32), 12508–12517) demonstrated a silent …
(trippBAP) 3, 2) complex (Inorg. Chem. 2022, 61 (32), 12508–12517) demonstrated a silent …
Uranium (III) and uranium (IV) meta-terphenyl thiolate complexes
We report the synthesis and characterization of crystalline uranium (IV) and uranium (III)
complexes supported by the bulky hexa-iso-propyl-m-terphenylthiolate ligand system …
complexes supported by the bulky hexa-iso-propyl-m-terphenylthiolate ligand system …