Tuning Magnetic Anisotropy in Co (II) Tetrahedral Carbazole-Modified Phosphine Oxide Single-Ion Magnets: Importance of Structural Distortion versus Heavy-Ion …
Three mononuclear cobalt (II) tetrahedral complexes [Co (CzPh2PO) 2X2](CzPh2PO=(9H-
carbazol-9-yl) diphenylphosphine oxide and X= Cl (1), Br (2), I (3)) have been synthesized …
carbazol-9-yl) diphenylphosphine oxide and X= Cl (1), Br (2), I (3)) have been synthesized …
Role of Halide Ions in the Nature of the Magnetic Anisotropy in Tetrahedral CoII Complexes
A series of mononuclear tetrahedral CoII complexes with a general molecular formula
[CoL2X2][L= thiourea and X= Cl (1), Br (2) and I (3)] were synthesized and their structures …
[CoL2X2][L= thiourea and X= Cl (1), Br (2) and I (3)] were synthesized and their structures …
Purely spectroscopic determination of the spin Hamiltonian parameters in high-spin six-coordinated cobalt (II) complexes with large zero-field splitting
EY Misochko, AV Akimov, DV Korchagin… - Inorganic …, 2019 - ACS Publications
Accurate determination of the spin Hamiltonian parameters in transition-metal complexes
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …
with large zero-field splitting (ZFS) is an actual challenge in studying magnetic and …
Toward steric control of guest binding modality: a cationic Co (II) complex exhibiting cation binding and zero-field relaxation
TJ Ozumerzifon, I Bhowmick, WC Spaller… - Chemical …, 2017 - pubs.rsc.org
We present the syntheses and characterization of several salts of a trigonal prismatic cobalt
(II) complex with a 1, 3, 5-triaminocyclohexane (tach)-derived ditopic ligand. The air-and …
(II) complex with a 1, 3, 5-triaminocyclohexane (tach)-derived ditopic ligand. The air-and …
Tuning magnetic anisotropy through ligand substitution in five-coordinate co (ii) complexes
D Schweinfurth, J Krzystek, M Atanasov… - Inorganic …, 2017 - ACS Publications
Understanding the origin of magnetic anisotropy and having the ability to tune it are
essential needs of the rapidly developing field of molecular magnetism. Such attempts at …
essential needs of the rapidly developing field of molecular magnetism. Such attempts at …
A family of related Co (II) terpyridine compounds exhibiting field induced single-molecule magnet properties
We describe the syntheses, crystal structures and magnetic properties of several Co (II)
complexes containing 4′-pyrrolidine-2, 2′: 6′, 2 ″-terpyridine (pyrtpy) or 4 …
complexes containing 4′-pyrrolidine-2, 2′: 6′, 2 ″-terpyridine (pyrtpy) or 4 …
Determination of zero-field splitting in Co 2+ halide complexes with magnetic and far-IR measurements
Three penta-coordinate Co2+ complexes with halide substitutes were synthesized. Their
zero-field splitting (ZFS) parameters were determined by fitting dc magnetic data and far …
zero-field splitting (ZFS) parameters were determined by fitting dc magnetic data and far …
Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes
AJ Mantanona, DR Tolentino, KS Cay… - Dalton …, 2020 - pubs.rsc.org
The first examples of Co (II) mesoionic carbene complexes (CoX2DippMIC2; X= Cl−, Br−, I−)
demonstrate a new electronic perturbation on tetrahedral Co (II) complexes. Using …
demonstrate a new electronic perturbation on tetrahedral Co (II) complexes. Using …
Anionic guest-dependent slow magnetic relaxation in Co (ii) tripodal iminopyridine complexes
CM Klug, TJ Ozumerzifon, I Bhowmick… - Dalton …, 2019 - pubs.rsc.org
We report the syntheses and magnetic property characterizations of four mononuclear cobalt
(II) complex salts featuring a tripodal iminopyridine ligand with external anion receptor …
(II) complex salts featuring a tripodal iminopyridine ligand with external anion receptor …
Field-induced slow relaxation of magnetization in the S= 3/2 octahedral complexes trans-[Co {(OPPh 2)(EPPh 2) N} 2 (dmf) 2], E= S, Se: effects of Co–Se vs. Co–S …
E Ferentinos, M Xu, A Grigoropoulos… - Inorganic Chemistry …, 2019 - pubs.rsc.org
The synthesis and the structural characterization of the octahedral trans-[Co
{(OPPh2)(EPPh2) N} 2 (dmf) 2], E= S (1), Se (2), complexes is described. These complexes …
{(OPPh2)(EPPh2) N} 2 (dmf) 2], E= S (1), Se (2), complexes is described. These complexes …