Hydrides of the main-group metals: New variations on an old theme
S Aldridge, AJ Downs - Chemical reviews, 2001 - ACS Publications
For an atom with such a uniquely simple electronic makeup, hydrogen shows remarkable
mutability as a ligand. As a one-electron substituent with no significant potential for π-type …
mutability as a ligand. As a one-electron substituent with no significant potential for π-type …
Group 13 metal (Al, Ga, In, Tl) complexes supported by heteroatom-bonded carbene ligands
The present contribution comprehensively reviews the synthesis, structural characterization
and current applications of group 13 metal complexes supported by heteroatom-bonded …
and current applications of group 13 metal complexes supported by heteroatom-bonded …
The First Structurally Characterized Metal–SeH Compounds: [LAl(SeH)2] and [L(HSe)AlSeAl(SeH)L]
C Cui, HW Roesky, H Hao, HG Schmidt… - Angewandte …, 2000 - Wiley Online Library
Unabhängig von der Menge an verwendetem Selen reagiert das Dihydrid 1 (Ar= 2, 6-iPr 2 C
6 H 3) mit diesem zu 2. In Lösung findet eine intermolekulare Eliminierung von H 2 Se statt …
6 H 3) mit diesem zu 2. In Lösung findet eine intermolekulare Eliminierung von H 2 Se statt …
Addition of Hydrogen or Ammonia to a Low‐Valent Group 13 Metal Species at 25° C and 1 Atmosphere
Z Zhu, X Wang, Y Peng, H Lei… - Angewandte Chemie …, 2009 - Wiley Online Library
Mild‐mannered: The low‐valent aryl gallium (I) species: GaAr′(Ar′= 2, 6‐(2, 6‐iPr2C6H3)
2C6H3) undergoes addition to H2 or NH3 at room temperature and one atmosphere of …
2C6H3) undergoes addition to H2 or NH3 at room temperature and one atmosphere of …
Advances in the chemistry of Lewis base adducts of alane and gallane
MG Gardiner, CL Raston - Coordination chemistry reviews, 1997 - Elsevier
Tertiary amine adducts of alane show a diverse range of structures based on four and five
coordinate species, hydride bridging dimeric and polymeric species, and ionic species …
coordinate species, hydride bridging dimeric and polymeric species, and ionic species …
The chemistry of Group 13/15 compounds (III–V compounds) with the higher homologues of Group 15, Sb and Bi
S Schulz - Coordination Chemistry Reviews, 2001 - Elsevier
Sb (SiMe3) 3 reacts with R3M (R= Alkyl, M= Al, Ga, In) to form simple Lewis acid–base
adducts R3M← SbR′ 3. Reactions with R2MCl (R= Me, Et, t-Bu) do not give uniform …
adducts R3M← SbR′ 3. Reactions with R2MCl (R= Me, Et, t-Bu) do not give uniform …
Preparation, Characterization, and Reactivity of the Stable Indium Trihydride Complex [InH3{CN(Mes)C2H2N(Mes)}]
CD Abernethy, ML Cole, C Jones - Organometallics, 2000 - ACS Publications
Reaction of either LiInH4 or [InH3 (NMe3)] with the Arduengo-type carbene: CN (Mes)
C2H2N (Mes), Mes= C6H2Me3-2, 4, 6, affords the indium trihydride complex [InH3 {CN …
C2H2N (Mes), Mes= C6H2Me3-2, 4, 6, affords the indium trihydride complex [InH3 {CN …
Main group coordination chemistry at low temperatures: A review of matrix isolated Group 12 to Group 18 complexes
NA Young - Coordination Chemistry Reviews, 2013 - Elsevier
The available data on main group (Groups 12–18) Lewis acid–base, donor–acceptor,
charge-transfer and van der Waals complexes stabilised by matrix isolation techniques are …
charge-transfer and van der Waals complexes stabilised by matrix isolation techniques are …
Synthesis, characterization and reactivity of an imidazolin-2-iminato aluminium dihydride
D Franz, E Irran, S Inoue - Dalton Transactions, 2014 - pubs.rsc.org
The reaction of bis (2, 6-diisopropylphenyl) imidazolin-2-imine (LH, 1) with Me3N· AlH3
furnishes {μ-LAlH2} 2 (2). The marked tendency of 2 to release its hydride substituents is …
furnishes {μ-LAlH2} 2 (2). The marked tendency of 2 to release its hydride substituents is …
Oxidative addition of an imidazolium cation to an anionic gallium (I) N-heterocyclic carbene analogue: Synthesis and characterisation of novel gallium hydride …
The reactions of N-heterocyclic carbenes and imidazolium salts towards an anionic gallium
(I) heterocycle,[: Ga {[N (Ar) C (H)] 2}]−, Ar= C6H3Pr2i-2, 6, have been studied. No reactions …
(I) heterocycle,[: Ga {[N (Ar) C (H)] 2}]−, Ar= C6H3Pr2i-2, 6, have been studied. No reactions …