ReI (CO) 3 complexes with diimine ligands synthesized in situ

F Villafañe - Coordination Chemistry Reviews, 2017 - Elsevier
This work covers the coupling reactions of monodentate ligands coordinated to the “Re I
(CO) 3” moiety to afford in situ new bidentate diimine ligands. Similar reactions leading to …

Formation of C–C bonds for the production of bio-alkanes under mild conditions

J Xin, S Zhang, D Yan, O Ayodele, X Lu, J Wang - Green Chemistry, 2014 - pubs.rsc.org
It is of crucial importance to form C–C bonds between biomass-derived compounds for the
production of bio-alkanes from biomass. In this study, it was found that C–C bonds can be …

Rhenium-catalysed hydroboration of aldehydes and aldimines

R Arévalo, CM Vogels, GA MacNeil, L Riera… - Dalton …, 2017 - pubs.rsc.org
The first examples for the rhenium-catalysed hydroboration of aldehydes, ketones and
aldimines, including heteroaromatic quinoline, are reported herein. Reactions are …

Switching the Photoreactions of Ir (III) Diamine Complexes between C–N Coupling and Dehydrogenation under Visible Light Irradiation

XK Huang, LP Li, HY Zhou, MF Xiong, JY Fan… - Inorganic …, 2022 - ACS Publications
The selective photoreactions under mild conditions play an important role in synthetic
chemistry. Herein, efficient and mild protocols for switching the photoreactions of Ir (III) …

Evidence of boride–borylene ligand-tautomerism leading to a remote C–C-bond and concomitant boryl ligand formation

FU Wehmeyer, Y Li, A Schlossarek, Z Ke… - Dalton Transactions, 2024 - pubs.rsc.org
The formation of a rhodium pincer-type complex with a boron-based donor ligand and its
reactivity are reported. The starting complex contains a formal borylene moiety, stabilised by …

Obtaining a high value branched bio-alkane from biomass-derived levulinic acid using RANEY® as hydrodeoxygenation catalyst

B Lu, J Li, G Lv, Y Qi, Y Wang, T Deng, X Hou… - RSC advances, 2016 - pubs.rsc.org
Compared to 5-HMF (C6H6O3), angelica lactone (C5H6O2) is a platform compound that
has more potential for biomass-derived high performance bio-alkane fuel production due to …

Influence of Functionalized Pyridine Ligands on the Radio/Chemical Behavior of [MI(CO)3]+ (M = Re and 99mTc) 2 + 1 Complexes

TR Hayes, PA Lyon, CL Barnes, S Trabue… - Inorganic …, 2015 - ACS Publications
While a number of chelate strategies have been developed for the organometallic precursor
fac-[MI (OH2) 3 (CO) 3]+(M= Re, 99mTc), a unique challenge has been to improve the …

A potential novel and general route for bromide replacement in diimine ReI tricarbonyl complexes leading to carboxylates: The effect in luminescence

N Pizarro, M Saldías, B Galaz, D Donoso, C Muñoz… - Polyhedron, 2022 - Elsevier
Abstract The reaction of the 3, 5-dimethylpyrazolyl-pyridazine-6-carboxylic acid (Me 2
LCOOH) or pyrazolyl-pyridazine-6-carboxylic acid (LCOOH) with [(THF)(CO) 3 Re (µ-Br) 2 …

Diastereoselective Photoreaction of Ir(III) Amine Complexes for Generation of New Multidentate Ligands in situ via a Postcoordinated Interligand‐Coupling Strategy

XY Chen, SY Yao, LP Li, BH Ye - Chinese Journal of Chemistry, 2021 - Wiley Online Library
Main observation and conclusion The diastereoselective photoreactions of Ir (III)‐amine and
Ir (III)‐diamine complexes are observed in the presence of O2. The Ʌ‐[Ir (pq) 2 (R …

Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear Complex of Ruthenium and Cobalt

M Nagaoka, T Kawashima, H Suzuki, T Takao - Organometallics, 2016 - ACS Publications
The dehydrogenative coupling of 4-substituted pyridines catalyzed by a heterometallic
trinuclear complex composed of Ru and Co,(Cp* Ru) 2 (Cp* Co)(μ-H) 3 (μ3-H)(1, Cp*= η5 …