[HTML][HTML] Recent progress in base-catalyzed isomerization of D-glucose into D-fructose

I Delidovich - Current Opinion in Green and Sustainable Chemistry, 2021 - Elsevier
Abstract Development of a catalytic process for isomerization of D-glucose into D-fructose
presents a crucial step for valorization of lignocellulosic feedstocks. This review focuses on …

Solar-driven glucose isomerization into fructose via transient lewis acid–base active sites

J Wang, H Zhao, B Zhu, S Larter, S Cao, J Yu… - ACS …, 2021 - ACS Publications
The selective glucose isomerization to fructose is an essential step for various industrial
biofuels and biochemicals production. However, current biological and acid–base catalysis …

Toward understanding base-catalyzed isomerization of saccharides

I Delidovich - Acs Catalysis, 2023 - ACS Publications
This Perspective addresses recent advances in isomerization of aldoses into ketoses
catalyzed by bases. In recent years, catalytic activity of a number of bases was reported, but …

Catalytic processes for biomass-derived platform molecules valorisation

M Ventura, A Marinas, ME Domine - Topics in Catalysis, 2020 - Springer
Nowadays, biomass is an interesting raw material for chemical industry, and the valorisation
of its derivatives becomes in a sustainable alternative against to the depletion of fossil …

One‐Pot Conversion of Glucose into 5‐Hydroxymethylfurfural using MOFs and Brønsted‐Acid Tandem Catalysts

M Lara‐Serrano, S Morales‐delaRosa… - Advanced …, 2022 - Wiley Online Library
The direct conversion reaction of glucose to 5‐hydroxymethylfurfural (HMF) is studied using
metal organic framework (MOF) as Lewis‐acid catalysts and a polyoxometalate (POM) …

Isomerization of glucose to fructose catalyzed by metal–organic frameworks

M Lara-Serrano, S Morales-delaRosa… - Sustainable Energy & …, 2021 - pubs.rsc.org
The isomerization reaction of glucose to fructose was studied using five selected metal–
organic frameworks (MOFs) as catalysts and a mixture of γ-valerolactone and 10% H2O as …

Catalytic Epimerization of Glucose to Mannose

J Wan, P Chu, X Wang, Z Sun, W Zhang… - ACS Sustainable …, 2024 - ACS Publications
Conversion of largely abundant glucose to other commercially important sugars has
attracted worldwide attention from both academia and industry. As one of the most important …

Study of base-catalyzed isomerization of d-glucose with a focus on reaction kinetics

M Fischer, P Drabo, I Delidovich - Reaction Kinetics, Mechanisms and …, 2022 - Springer
We explored the isomerization of d-glucose into d-fructose using the simplest possible base
catalyst, aqueous NaOH, to maintain a constant pH value during the reaction. Under the …

What are the catalytically active species for aqueous-phase isomerization of D-glucose into D-fructose in the presence of alkaline earth metal (hydr) oxides?

P Drabo, M Fischer, V Toussaint, F Flecken… - Journal of …, 2021 - Elsevier
The isomerization of D-glucose into D-fructose presents a key transformation in the concept
of cellulose valorization. Herein, we considered the isomerization of D-glucose into D …

Unraveling the reaction mechanism and active sites of metal–organic frameworks for glucose transformations in water: experimental and theoretical studies

S Rojas-Buzo, A Corma, M Boronat… - ACS Sustainable …, 2020 - ACS Publications
The catalytic performance of two different MOFs, UiO-66 and MOF-808, containing Lewis
acid active sites has been evaluated for the transformation of glucose in water and …