[HTML][HTML] Recent progress in base-catalyzed isomerization of D-glucose into D-fructose
I Delidovich - Current Opinion in Green and Sustainable Chemistry, 2021 - Elsevier
Abstract Development of a catalytic process for isomerization of D-glucose into D-fructose
presents a crucial step for valorization of lignocellulosic feedstocks. This review focuses on …
presents a crucial step for valorization of lignocellulosic feedstocks. This review focuses on …
Solar-driven glucose isomerization into fructose via transient lewis acid–base active sites
The selective glucose isomerization to fructose is an essential step for various industrial
biofuels and biochemicals production. However, current biological and acid–base catalysis …
biofuels and biochemicals production. However, current biological and acid–base catalysis …
Toward understanding base-catalyzed isomerization of saccharides
I Delidovich - Acs Catalysis, 2023 - ACS Publications
This Perspective addresses recent advances in isomerization of aldoses into ketoses
catalyzed by bases. In recent years, catalytic activity of a number of bases was reported, but …
catalyzed by bases. In recent years, catalytic activity of a number of bases was reported, but …
Catalytic processes for biomass-derived platform molecules valorisation
Nowadays, biomass is an interesting raw material for chemical industry, and the valorisation
of its derivatives becomes in a sustainable alternative against to the depletion of fossil …
of its derivatives becomes in a sustainable alternative against to the depletion of fossil …
One‐Pot Conversion of Glucose into 5‐Hydroxymethylfurfural using MOFs and Brønsted‐Acid Tandem Catalysts
M Lara‐Serrano, S Morales‐delaRosa… - Advanced …, 2022 - Wiley Online Library
The direct conversion reaction of glucose to 5‐hydroxymethylfurfural (HMF) is studied using
metal organic framework (MOF) as Lewis‐acid catalysts and a polyoxometalate (POM) …
metal organic framework (MOF) as Lewis‐acid catalysts and a polyoxometalate (POM) …
Isomerization of glucose to fructose catalyzed by metal–organic frameworks
M Lara-Serrano, S Morales-delaRosa… - Sustainable Energy & …, 2021 - pubs.rsc.org
The isomerization reaction of glucose to fructose was studied using five selected metal–
organic frameworks (MOFs) as catalysts and a mixture of γ-valerolactone and 10% H2O as …
organic frameworks (MOFs) as catalysts and a mixture of γ-valerolactone and 10% H2O as …
Catalytic Epimerization of Glucose to Mannose
J Wan, P Chu, X Wang, Z Sun, W Zhang… - ACS Sustainable …, 2024 - ACS Publications
Conversion of largely abundant glucose to other commercially important sugars has
attracted worldwide attention from both academia and industry. As one of the most important …
attracted worldwide attention from both academia and industry. As one of the most important …
Study of base-catalyzed isomerization of d-glucose with a focus on reaction kinetics
M Fischer, P Drabo, I Delidovich - Reaction Kinetics, Mechanisms and …, 2022 - Springer
We explored the isomerization of d-glucose into d-fructose using the simplest possible base
catalyst, aqueous NaOH, to maintain a constant pH value during the reaction. Under the …
catalyst, aqueous NaOH, to maintain a constant pH value during the reaction. Under the …
What are the catalytically active species for aqueous-phase isomerization of D-glucose into D-fructose in the presence of alkaline earth metal (hydr) oxides?
P Drabo, M Fischer, V Toussaint, F Flecken… - Journal of …, 2021 - Elsevier
The isomerization of D-glucose into D-fructose presents a key transformation in the concept
of cellulose valorization. Herein, we considered the isomerization of D-glucose into D …
of cellulose valorization. Herein, we considered the isomerization of D-glucose into D …
Unraveling the reaction mechanism and active sites of metal–organic frameworks for glucose transformations in water: experimental and theoretical studies
The catalytic performance of two different MOFs, UiO-66 and MOF-808, containing Lewis
acid active sites has been evaluated for the transformation of glucose in water and …
acid active sites has been evaluated for the transformation of glucose in water and …