Levulinic acid (LA) is one of the most prominent biomass‐derived chemical building blocks
that can be transformed into specialty chemicals like fuels, solvents, monomers for polymers …

Frustrated Lewis Pairs (FLPs) are derived from simple combinations of Lewis acids (electron
acceptors) and Lewis bases (electron donors), in which steric demands prevent from forming …

The development of sustainable polymers that possess useful material properties
competitive with existing petroleum-derived polymers is a crucial goal but remains a …

Ten years have passed since the conception of what was termed Lewis pair polymerization
(LPP) that employs Lewis acid and base in pairs to not only activate monomers but also …

Precision synthesis of cyclic polymers with predictable molecular weight and low dispersity
is a challenging task, particularly concerning cyclic polar vinyl polymers through a rapid …

This work utilizes frustrated Lewis pairs consisting of tethered bis‐organophosphorus
superbases and a bulky organoaluminum to furnish the highly efficient synthesis of well …

This contribution reports the efficient conversion of γ‐valerolactone and its derivatives,
abundant but unexplored renewable feedstocks, into sustainable and degradable …

Zn (HMDS) 2 as a simple, biocompatible, efficient, and supporting ligand-free metal catalyst
has been achieved for polyesters synthesis and degradation. The catalyst not only has a …

Lewis pair polymerization has demonstrated its unique advantages and powerful capability
in polymer synthesis. Here we employ strong nucleophilic N‐heterocyclic olefin (NHO) and …

With the development of controlled polymerisation, almost all polymerisation strategies have
been successfully transplanted to surface-initiated polymerisation. The resulting polymer …