The number of rare earth (RE) starting materials used in synthesis is staggering, ranging
from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl …

The divalent metallocene complexes Ln (CpiPr5) 2 (Ln= Tb, Dy) were synthesized through
the KC8 reduction of Ln (CpiPr5) 2I intermediates and represent the first examples of …

A small but growing number of molecular compounds have been isolated featuring divalent
lanthanides with 4f n 5d z 21 electron configurations. While the majority of these possess …

This review summarizes the progress in organo-f-element chemistry during the year 2017.
This year witnessed a significant increase of publications in the fields of organolanthanide …

The pentalene-ligated dysprosium complex [(η8-Pn†) Dy (Cp*)](1Dy)(Pn†=[1, 4-(iPr3Si)
2C8H4] 2−) and its magnetically dilute analogue are single-molecule magnets, with energy …

Reduction of ArBIG-bian (1, 1, 2-bis [(2, 6-dibenzhydryl-4-methylphenyl) imino]
acenaphthene) with an excess of samarium in tetrahydrofuran (thf) and crystallization of the …

Two new organometallic cyclooctatetraenyl complexes of the type [M2 (COT) 3 (THF) 2](M=
Y and La) have been prepared, using optimized synthetic procedures, and fully …

A series of titanium complexes containing the permethylpentalene ligand (C 8 Me 6 2−;
Pn∗)–Pn∗ Ti (O-2, 6-Me-C 6 H 3) Cl (1), Pn∗ Ti (O-2, 4-t Bu-C 6 H 3) Cl (2), Pn∗ Ti (O t Bu) …

In recent years, collaborative studies that leverage experimental synthesis, spectroscopic
characterization, and electronic structure analysis have enabled significant advances in f …

In recent years, collaborative studies that leverage experimental synthesis, spectroscopic
characterization, and electronic structure analysis have enabled significant advances in f …