Gold-catalyzed reactions of C–H bonds

R Skouta, CJ Li - Tetrahedron, 2008 - Elsevier
At the beginning of the last century, organic chemists began to use transition metal catalysts
for forming carbon–carbon and carbon–heteroatom bonds. Since then, the formation of …

[HTML][HTML] Cancer molecular biology and strategies for the design of cytotoxic gold (I) and gold (III) complexes: a tutorial review

D van der Westhuizen, DI Bezuidenhout… - Dalton …, 2021 - pubs.rsc.org
This tutorial review highlights key principles underpinning the design of selected
metallodrugs to target specific biological macromolecules (DNA and proteins). The review …

Antitumor properties of some 2-[(dimethylamino) methyl] phenylgold (III) complexes

RG Buckley, AM Elsome, SP Fricker… - Journal of medicinal …, 1996 - ACS Publications
Four analogues of the gold (III) complex [AuCl2 (damp)](1)(damp= 2-[(dimethylamino)
methyl] phenyl) have been evaluated for antitumor activity. The compounds have structural …

Chemical and biological studies of dichloro (2-((dimethylamino) methyl) phenyl) gold (III)

RV Parish, BP Howe, JP Wright, J Mack… - Inorganic …, 1996 - ACS Publications
Several new organogold (III) derivatives of the type [AuX2 (damp)](damp= o-
C6H4CH2NMe2) have been prepared [X= CN, SCN, dtc, or X2= tm; dtc= R2NCS2 (R= Me …

Application of 2,6-Diphenylpyridine as a Tridentate [CNC] Dianionic Ligand in Organogold(III) Chemistry. Structural and Spectroscopic Properties of Mono- and …

KH Wong, KK Cheung, MCW Chan, CM Che - Organometallics, 1998 - ACS Publications
The synthesis of a series of mono-and binuclear cyclometalated gold (III) complexes
containing the tridentate C∧ N∧ C ligand (HC∧ N∧ CH= 2, 6-diphenylpyridine) was …

[HTML][HTML] Stoichiometric to catalytic reactivity of the aryl cycloaurated species with arylboronic acids: insight into the mechanism of gold-catalyzed oxidative C (sp 2)–H …

Q Wu, C Du, Y Huang, X Liu, Z Long, F Song… - Chemical Science, 2015 - pubs.rsc.org
Based on the well-defined five-membered aryl gold (III) complexes,[Au (tpy) X2](3a and 3b)
and [AuBr (Ph)(tpy)](7), as well as the aryl gold (III) complex [AuCl2 (Ph)(tpy)](8)(tpy= 2-(o …

Organogold (III) metallacyclic chemistry. Part 4. Synthesis, characterisation, and biological activity of gold (III)-thiosalicylate and-salicylate complexes

MB Dinger, W Henderson - Journal of organometallic chemistry, 1998 - Elsevier
The silver (I) oxide mediated reactions of the gold (III) dichloride complex [{C6H3 (CH2NMe
2)-2-(OMe)-5} A uCl2] 2a with thiosalicylic or salicylic acid gives the respective complexes …

Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold (III)− Monomethyl Complex

VJ Scott, JA Labinger, JE Bercaw - Organometallics, 2010 - ACS Publications
Oxidation of (Idipp) AuMe (Idipp= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene) with I2
gives a monomethyl Au (III) complex,(Idipp) AuI2Me, which decomposes cleanly to MeI and …

A Bis(ortho-amine)aryl−Gold(I) Compound as an Efficient, Nontoxic, Arylating Reagent

M Contel, M Stol, MA Casado, GPM van Klink… - …, 2002 - ACS Publications
A novel strategy for the synthesis of bis (ortho-amine) chelated monoanionic bisaminoaryl−
metal complexes is presented. This method constitutes the exchange of a monoanionic …

[HTML][HTML] Selective anticancer and antimicrobial metallodrugs based on gold (Iii) dithiocarbamate complexes

E Abás, D Aguirre-Ramírez, M Laguna, L Grasa - Biomedicines, 2021 - mdpi.com
New dithiocarbamate cycloaurated complexes have been synthesized and their
physicochemical and in vitro antitumor properties have been evaluated. All the performed …