Entropy plays a pivotal role in catalysis, and extensive research efforts have been directed to
understanding the enthalpy-entropy relationship that defines the reaction pathways of …

The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …

Abstract Structure–reactivity relationships for nanoparticle-based catalysts have been
greatly influenced by the study of catalytic materials with either supported isolated metal …

Ethanol, as one of the important bulk chemicals, is widely used in modern society. It can be
produced by fermentation of sugar, petroleum refining, or conversion of syngas (CO/H2) …

The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …

Microporous zeolite-type materials, with crystalline porous structures formed by well-defined
channels and cages of molecular dimensions, have been widely employed as …

Decentralized chemical plants close to circular carbon sources will play an important role in
shaping the postfossil society. This scenario calls for carbon technologies which valorize …

Chemical reactivity and sorption in zeolites are coupled to confinement and—to a lesser
extent—to the acid strength of Brønsted acid sites (BAS). In presence of water the zeolite …

Heterogeneous catalysts often undergo structural transformations when they operate under
thermal reaction conditions. These transformations are reflected in their evolving catalytic …

Zeolites are versatile and fascinating materials which are vital for a wide range of industries,
due to their unique structural and chemical properties, which are the basis of applications in …