Metal–organic frameworks for one-step ethylene purification from multi-component hydrocarbon mixtures

Y Han, L Wang, Y Zhang, B Chen - Coordination Chemistry Reviews, 2025 - Elsevier
Abstract Ethylene (C 2 H 4) is extremely important as one of the world's largest chemical
commodity. A variety of light hydrocarbon gases (C 1-C 3) and carbon dioxide (CO 2) coexist …

Ethane/Ethylene Separations in Flexible Diamondoid Coordination Networks via an Ethane-Induced Gate-Opening Mechanism

SM Wang, M Shivanna, ST Zheng, T Pham… - Journal of the …, 2024 - ACS Publications
Separating ethane (C2H6) from ethylene (C2H4) is an essential and energy-intensive
process in the chemical industry. Here, we report two flexible diamondoid coordination …

Stimulus-responsive hydrogen-bonded organic frameworks: Construction strategies, research progress and applications

W Wei, L He, G Han, Y Lu, S Shi, Z Yuan… - Coordination Chemistry …, 2024 - Elsevier
Stimulus-responsive hydrogen-bonded organic frameworks (HOFs) can respond to specific
physical or chemical stimuli by exhibiting reversible changes in structure, conductivity, color …

Synergistic C2H2 Binding Sites in Hydrogen‐Bonded Supramolecular Framework for One‐Step C2H4 Purification from Ternary C2 Mixture

Z Ji, Q Li, Y Zhou, R Krishna, M Hong… - Angewandte Chemie …, 2024 - Wiley Online Library
Purification of C2H4 from the ternary C2 hydrocarbon mixture in one step is of critical
significance but still extremely challenging according to its intermediate physical properties …

A microporous Cd (II)-MOF for efficient separation of trace SO2 from SO2/CO2/N2 mixture

SQ Gang, ZY Liu, YN Bian, R Wang, JL Du - Separation and Purification …, 2024 - Elsevier
Trace SO 2 removal of flue gas is very important to prevent environmental pollution. Porous
Metal-Organic Frameworks (MOFs) possess natural advantages for the mixed gas …

Mechanochemical “Cage‐on‐MOF” Strategy for Enhancing Gas Adsorption and Separation through Aperture Matching

Y Liang, G Xie, KK Liu, M Jin, Y Chen… - Angewandte Chemie …, 2024 - Wiley Online Library
Post‐modification of porous materials with molecular modulators has emerged as a well‐
established strategy for improving gas adsorption and separation. However, a notable …

Metal-cluster-powered ultramicropore alliance in pore-space-partitioned metal-organic frameworks for benchmark one-step ethylene purification

SY Li, SC Fan, P Zhang, WY Yuan, Y Wang, QG Zhai - Chem, 2024 - cell.com
Ultra-fine structural tuning of metal-organic frameworks (MOFs) using isoreticular chemistry
is helpful in designing ideal gas adsorbents but is extremely challenging. Known strategies …

Stepwise customizing pore environments of C2H2-selective frameworks for one-step C2H4 acquisition from ternary mixtures

S Zou, C Chen, Z Di, Y Liu, H Li, Y Li, R Krishna… - Separation and …, 2025 - Elsevier
One-step purification of C 2 H 4 from ternary C 2 H 2/C 2 H 4/C 2 H 6 mixture is crucial but
challenging since the primary physical properties of C 2 H 4 all fall between C 2 H 2 and C 2 …

Nonpolar microporous Metal-Organic framework decorated with multiple functional sites for efficient Ethane/Ethylene separation

Z Zhu, J Xiao, M Zhang, Y Wang, KX Yao… - Separation and …, 2025 - Elsevier
Efficiently achieving one-step adsorption separation of ethylene (C 2 H 4) from ethane (C 2
H 6) is a highly sought-after yet challenging task in the petrochemical industry. This …

A Propeller-Like Ligand-Directed Construction of a Tetranuclear Cerium-Organic Framework for Single-Step Ethylene Purification from Ternary C2 Mixtures

N Yang, HX Li, L Ritter, GT Du, XA Guo… - Inorganic …, 2024 - ACS Publications
The efficient single-step purification of ethylene from ternary C2 mixtures containing ethane
and acetylene is challenging and demanding. Herein, we introduce a novel cerium-based …