Metal stereogenicity in asymmetric transition metal catalysis

PS Steinlandt, L Zhang, E Meggers - Chemical Reviews, 2023 - ACS Publications
Chiral transition metal catalysts represent a powerful and economic tool for implementing
stereocenters in organic synthesis, with the metal center providing a strong chemical …

Borrowing hydrogen for organic synthesis

BG Reed-Berendt, DE Latham, MB Dambatta… - ACS Central …, 2021 - ACS Publications
Borrowing hydrogen is a process that is used to diversify the synthetic utility of commodity
alcohols. A catalyst first oxidizes an alcohol by removing hydrogen to form a reactive …

Transition metal-catalysed molecular n-doping of organic semiconductors

H Guo, CY Yang, X Zhang, A Motta, K Feng, Y Xia… - Nature, 2021 - nature.com
Chemical doping is a key process for investigating charge transport in organic
semiconductors and improving certain (opto) electronic devices,,,,,,,–. N (electron)-doping is …

Recent catalytic routes for the preparation and the upgrading of biomass derived furfural and 5-hydroxymethylfurfural

C Xu, E Paone, D Rodríguez-Padrón… - Chemical Society …, 2020 - pubs.rsc.org
Furans represent one of the most important classes of intermediates in the conversion of non-
edible lignocellulosic biomass into bio-based chemicals and fuels. At present, bio-furan …

Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms

L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …

Nickel and palladium catalysis: Stronger demand than ever

VM Chernyshev, VP Ananikov - Acs Catalysis, 2022 - ACS Publications
Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

Continuous Flow Upgrading of Selected C2–C6 Platform Chemicals Derived from Biomass

R Gerardy, DP Debecker, J Estager, P Luis… - Chemical …, 2020 - ACS Publications
The ever increasing industrial production of commodity and specialty chemicals inexorably
depletes the finite primary fossil resources available on Earth. The forecast of population …

Carbon-based single-atom catalysts for advanced applications

MB Gawande, P Fornasiero, R Zbořil - Acs Catalysis, 2020 - ACS Publications
Carbon-based materials are widely employed as metal-free catalysts or supports in
catalysis, energy, and ecological applications because of their interesting properties …

Production of levulinic acid and alkyl levulinates: a process insight

DDM Di Bucchianico, Y Wang, JC Buvat, Y Pan… - Green …, 2022 - pubs.rsc.org
The use of lignocellulosic biomass in the chemical industry has increased due to its non-
competition with the food sector. Several platform molecules can be produced from this …

First-row transition metal (de) hydrogenation catalysis based on functional pincer ligands

L Alig, M Fritz, S Schneider - Chemical reviews, 2018 - ACS Publications
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …