[HTML][HTML] An overview about synthetic high charge micas and their uses

LH Oliveira, DB França, AIS Moraes… - Applied Clay …, 2024 - Elsevier
Synthetic micas are materials with interesting properties that combine high charge (high
cation exchange capacity) with swelling capacity. Among the various methods for …

NMR spectroscopy of minerals and allied materials

SE Ashbrook, DM Dawson - 2016 - books.rsc.org
Nuclear Magnetic Resonance (NMR) spectroscopy has played an important role over many
years in understanding the structure and reactivity of minerals. The advent of highresolution …

Bionanocomposites based on chitosan intercalation in designed swelling high-charged micas

MD Alba, A Cota, FJ Osuna, E Pavón, AC Perdigón… - Scientific Reports, 2019 - nature.com
Bionanocomposites based on layered inorganic components, as clays, and polymers of
biological origin, as chitosan, have a major impact in medical and environmental fields …

Interrelations of structure, electric surface charge, and hydrophobicity of organo-mica and–montmorillonite, tailored with quaternary or primary amine cations …

M del Mar Orta, FM Flores, CF Morantes… - Materials Chemistry and …, 2019 - Elsevier
In this work, organo-montmorillonite (organo-Mt) and organo-synthetic mica (organo-mica),
obtained by quaternary or primary amine cations (octadecyltrimethylammonium (ODTMA) or …

Interaction of Hydrated Cations with Mica-n (n = 2, 3 and 4) Surface

E Pavón, MA Castro, A Cota, FJ Osuna… - The Journal of …, 2014 - ACS Publications
High charged swelling micas, with layer charge between 2 and 4, have been found to
readily swell with water, and complete cation exchange (CEC) can be achieved. Because of …

Hydronium-promoted equilibrium mechanism for the alkali metal cation exchange reaction in Na-4-mica

M Park, HJ Kim, KS Kim, OW Duckworth… - The Journal of …, 2012 - ACS Publications
A general stoichiometric cation exchange mechanism does not fully explain the unique
exchange behaviors of Na-4-mica, the most highly charged swelling 2: 1 phyllosilicate …

Synthesis temperature effect on Na-Mica-4 crystallinity and heteroatom distribution

M Naranjo, MA Castro, A Cota, FJ Osuna… - Microporous and …, 2015 - Elsevier
The discovery of swelling brittle mica, Na-Mica-4, has been one of the most significant
advances in the pursuit for a material with high ion-exchange capacity. For technical …

An insight on the design of mercapto functionalized swelling brittle micas

FJ Osuna, E Pavón, MD Alba - Journal of colloid and interface science, 2020 - Elsevier
Surface modification of natural clay minerals with reagents containing metal chelating
groups has great environmental value. The functionalization by adsorption or grafting …

Synthesis and single crystal structure refinement of the one-layer hydrate of sodium brittle mica

H Kalo, W Milius, M Bräu, J Breu - Journal of Solid State Chemistry, 2013 - Elsevier
A sodium brittle mica with the ideal composition [Na4] inter [Mg6] oct [Si4Al4] tetO20F4 was
synthesized via melt synthesis in a gas tight crucible. This mica is unusual inasmuch as the …

Stabilization of alkali earth metal cations in Na-4-mica

JH Kim, HJ Kim, M Park - Applied clay science, 2014 - Elsevier
Abstract Na-4-mica, a highly charged swelling mica, has suffered from insufficient
understanding of some fundamental features such as partial layer collapse and …