Radical thioesterification via nickel-catalysed sensitized electron transfer

H Wang, Z Liu, A Das, P Bellotti, S Megow, F Temps… - Nature …, 2023 - nature.com
Multi-catalytic reaction modes have attracted widespread attention in synthetic chemistry.
The merger of nickel catalysis with photoredox catalysis has offered a powerful platform for …

Nickel Catalyzed Carbonylation/Carboxylation Sequence via Double CO2 Incorporation

R Giovanelli, L Lombardi, R Pedrazzani… - Organic …, 2023 - ACS Publications
A carbonylation–carboxylation synthetic sequence, via double CO2 fixation, is described.
The productive merger of a Ni-catalyzed cross-electrophile coupling manifold, with the use …

Efficient and Low‐Impact Acetalization Reactions in Deep Eutectic Solvents

D Arnodo, C Meazzo, S Baldino… - … A European Journal, 2023 - Wiley Online Library
The synthesis of acetals in acidic natural deep eutectic solvents (NADES), in which the
solvent itself participates in the catalytic promotion of the reaction, is reported herein. The …

[HTML][HTML] Palladium-catalyzed synthesis of carboxylic acid anhydrides from alkenes

A Ramakrishnan, SG Romeijn, E Bouwman - Journal of Catalysis, 2023 - Elsevier
Hydrocarbonylation of alkenes with nucleophiles–water, alcohols and amines, is widely
studied and implemented in synthesis of fine chemicals and natural products. Here, an …

PPh3/Selectfluor‐Mediated Transformation of Carboxylic Acids into Acid Anhydrides and Acyl Fluorides and Its Application in Amide and Ester Synthesis

Z Yang, S Chen, F Yang, C Zhang… - European Journal of …, 2019 - Wiley Online Library
By taking the advantage of PPh3/Selectfluor system, carboxylic acids are efficiently
converted into the pivotal intermediates acyloxyphosphonium ions that can selectively react …

Direct conversion of carboxylic acids to various nitrogen-containing compounds in the one-pot exploiting curtius rearrangement

A Kumar, N Kumar, R Sharma… - The Journal of …, 2019 - ACS Publications
Herein we report, a single-pot multistep conversion of inactivated carboxylic acids to various
N-containing compounds using a common synthetic methodology. The developed …

KF-catalyzed direct thiomethylation of carboxylic acids with DMSO to access methyl thioesters

DY Huang, HS Liu, EH Wang, M Peng… - Organic & …, 2024 - pubs.rsc.org
With dimethyl sulfoxide (DMSO) as the methylthio source, a KF-catalyzed strategy was
employed for the direct thiomethylation of carboxylic acids with DMSO for the preparation of …

Design, fabrication, and characterization of o-phenylenediamine surface-conjugated carbon quantum nanodots as a potential new bioactive formulation

G Karakus - Applied Nanoscience, 2023 - Springer
The aim of this study was to design and characterize a candidate molecule of biological
significance by synergistically combining the unique chemical properties, biocompatibility …

Palladium‐Catalyzed Synthesis of Carboxylic Acid Anhydrides from Alkenes via in situ Generated Carboxylic Acids

A Ramakrishnan, E Bouwman - ChemCatChem, 2024 - Wiley Online Library
We herein present a carbonylative strategy to synthesize carboxylic acid anhydrides from
alkenes from in situ generated carboxylic acids. Formic acid (FA) reacts with alkene and CO …

Decoration, Characterization and Antimicrobial Activity Evaluation of Novel Nano‐Based 1, 2‐Phenylenediamine Functionalized Maleic Anhydride‐Allylphenyl Ether …

G Karakus, M Atas - ChemistrySelect, 2023 - Wiley Online Library
Phenylenediamine (o‐PDA) is a well‐known fluorescent dye that enables the decoration of
next‐generation chemotherapeutics. A novel o‐PDA‐functionalized maleic anhydride‐allyl …