Sterically encumbered Lewis acid and Lewis base combinations do not undergo the
ubiquitous neutralization reaction to form “classical” Lewis acid/Lewis base adducts. Rather …

Abstract Die Kombination sterisch gehinderter Lewis‐Säuren und‐Basen führt nicht zur
üblichen Neutralisationsreaktion unter Bildung der “klassischen” Lewis‐Säure/Base …

While recent spectroscopic studies have established the presence of an interstitial carbon
atom at the center of the iron–molybdenum cofactor (FeMoco) of MoFe-nitrogenase, its role …

Names: Stradiotto, Mark, author.| Lundgren, Rylan, author. Title: Ligand design in metal
chemistry: reactivity and catalysis/[edited by] Mark Stradiotto, Rylan Lundgren. Description …

Our currently limited understanding of the mechanism of biological dinitrogen fixation [1]–ie
the reduction of N2 to two equivalents of ammonia by addition of protons and electrons …

Bond activation and catalysis are central to the development of a sustainable energy system.
Frustrated Lewis Pairs have conceptually revolutionized the activation of inert chemical …

Reversible, heterolytic addition of H2 across an iron–boron bond in a ferraboratrane with
formal hydride transfer to the boron gives iron-borohydrido-hydride complexes. These …

Terminal iron nitrides (Fe N) have been proposed as intermediates of (bio) catalytic
nitrogen fixation, yet experimental evidence to support this hypothesis has been lacking. In …

The reaction mechanism for the transition metal free direct hydrogenation of bulky imines
catalyzed by the Lewis acid B (C6F5) 3 is investigated in detail by quantum chemical …

The reactivity of the anionic dinitrogen complex [(TPB) Fe (N2)]−(TPB= tris [2-
(diisopropylphosphino) phenyl] borane) toward silicon electrophiles has been …