We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

For molecules with a singlet ground state, the population of triplet states is mainly possible
(a) by direct excitation and subsequent intersystem crossing or (b) by energy transfer from …

Radical/radical cross-coupling reactions represent an efficient and straightforward approach
for the construction of chemical bonds and accordingly have drawn increasing attention over …

Conspectus Transition-metal catalyzed cross-coupling reactions are fundamental reactions
in organic chemistry, facilitating strategic bond formations for accessing natural products …

Cross-coupling between two similar or identical functional groups to form a new C–C bond
is a powerful tool to rapidly assemble complex molecules from readily available building …

The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

A useful protocol for achieving decarboxylative cross-coupling (DCC) of redox-active esters
(RAE, isolated or generated in situ) and halo (hetero) arenes is reported. This pragmatically …

Carboxylic acids, the most versatile and ubiquitous diversity input used in medicinal
chemistry for canonical polar bond constructions such as amide synthesis, can now be …

The catalytic enantioselective construction of C (sp 3)− C (sp 3) bonds remains a substantial
challenge in organic synthesis. One particularly promising approach is the use of transition …

The merger of photoredox and transition-metal catalysis has evolved as a robust platform in
organic synthesis over the past decade. The stereoselective 1, 4-functionalization of 1, 3 …