Arynes are among the most active organic intermediates and have found numerous
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …

This tutorial review is aimed at highlighting recent developments in transition-metal-free
carbon–carbon and carbon–heteroatom bond-forming reactions utilizing a versatile class of …

About two decades after Kobayashi's discovery in 1983 of a very mild way of generating
highly reactive aryne intermediates, the synthetic community embraced o-(trimethylsilyl) aryl …

The challenges of the modern society and the growing demand of high-technology sectors
of industrial production bring about a new phase in the development of organic synthesis. A …

Oxaziridines constitute a subset of a class of versatile oxidants whose characteristic feature
is the presence of two electronegative heteroatoms within a strained three-membered ring …

抄録< jats: title> Abstract</jats: title>< jats: p> Recent studies of aryne chemistry have left
some unexplained details in their reactivity, reaction mechanisms, and structure‐activity …

AS–O bond insertion reaction of sulfoxides with arynes is reported. This reaction represents
a rare instance of semipolar single bond insertion in aryne chemistry. The study of …

Herein, we report a rare example of trapping arynes using in situ generated
aryltrifluoromethylnitrone to access an important class of trifluoromethylated benzoxazolines …

A distinctive N-substituent controlled electrophilic N-transfer of oxaziridines with donor–
acceptor cyclopropanes in the presence of MgI2 is reported. Contrary to earlier reports, the …

Pyrido [1, 2-a] indoles are known as medicinally and pharmaceutically important
compounds, but there is a lack of efficient methods for their synthesis. We report a …