C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

Based on the strategy of polarity reversal in the generation of free radicals derived from
diazo compounds, photocatalyzed multicomponent reactions (MCRs) of nitrogen aromatic …

A Rh (III)-catalyzed ortho C–H migratory insertion of N-nitrosoanilines with naphthoquinone
carbenes has been developed. The products were obtained in good yields under mild …

A catalyst-free synthetic approach to β-thiazole-fused 5, 10, 15, 20-tetraarylporphyrins via a
cascade reaction of nickel (II) or copper (II) 2-amido-3-bromo-5, 10, 15, 20 …

Phenolic biaryl and styryl moieties are important structural motifs in natural products,
pharmaceuticals, and functional materials. Traditional cross‐coupling often requires pre …

The diaryl ether represents a prevalent structural motif found in numerous biologically active
molecules. Herein, we describe a dirhodium-catalyzed C (sp2)–O cross coupling reaction …

Allylphenol is an important and ubiquitous structural motif in biologically active natural
products and pharmaceuticals. Herein, we report a Rh2 (esp) 2-catalyzed reaction of …

We report here a formal insertion of a metal carbene complex in a single carbon‐carbon
bond. This behavior occurs with the participation of an α‐imino gold carbene complex …

A synthetic method to prepare (E)-3-arylazoindoles efficiently that relies on the gold (I)-
catalysed azo coupling of 1, 2-and 1, 4-diazoquinones with 1H-indoles under mild reaction …

The diarylamine scaffold is common in bioactive molecules. Herein, we report a Ru (II)-
catalyzed C–N cross-coupling reaction of diazoquinones with arylamines, which provides …