Cold-Start NOx Mitigation by Passive Adsorption Using Pd-Exchanged Zeolites: From Material Design to Mechanism Understanding and System Integration

Y Li, D Chen, X Xu, X Wang, R Kang, M Fu… - Environmental …, 2023 - ACS Publications
It remains a major challenge to abate efficiently the harmful nitrogen oxides (NO x) in low-
temperature diesel exhausts emitted during the cold-start period of engine operation …

Superior performance in passive NOx adsorption over an Al-rich Beta zeolite supported palladium

J Li, K Fan, Y Shan, S Wang, J Zhang, W Fan… - Applied Catalysis B …, 2023 - Elsevier
Passive NO x adsorption (PNA) has been regarded as a new technology for NO x
elimination at low temperatures in heavy diesel vehicles (HDV) during the cold-start period …

[HTML][HTML] NO adsorption/desorption pathways over Pd/SSZ-13 low temperature NOx adsorbers investigated by operando FT-IR spectroscopy and microreactor study

R Matarrese, L Castoldi, S Morandi, P Ticali… - Applied Catalysis B …, 2023 - Elsevier
In this study a Pd-doped SSZ-13 zeolite sample is synthesized, characterized and evaluated
for potential use in the low-temperature NO x adsorption. TEM/HR-TEM and in-situ CO/NO …

Na co-cations promoted stability and activity of Pd/SSZ-13 for low-temperature NO adsorption

D Li, G Yang, M Chen, L Pang, Y Guo, J Yu… - Applied Catalysis B …, 2022 - Elsevier
The abatement of harmful nitrogen oxides (NO x) emission during vehicle cold start is
challenging. Passive NO x adsorbers (PNAs) have proven to effectively alleviate NO x …

An oxidation-adsorption site separation strategy for stabilizing Pd-Pt/SSZ-13 PNA materials under high CO pressure

C Wang, X Kang, Y Gu, F Gao - Chemical Engineering Journal, 2024 - Elsevier
Pd/SSZ-13 passive NOx adsorbers (PNAs) are effective in controlling NOx emissions during
the cold start phase of diesel engines, but palladium ions readily aggregate in the presence …

[HTML][HTML] Enhanced CO resistance of Pd/SSZ-13 for passive NOx adsorption

D Yao, PH Ho, RF Ilmasani, JC Wurzenberger… - Chemical Engineering …, 2023 - Elsevier
Passive NO x adsorption (PNA) is a novel technology to control NO x emissions during cold
start. However, the recent generation of PNA material, Pd/zeolite, suffers from major …

Mechanistic insight in the propylene derived distinct NO uptake and release behaviors on Pd/SSZ-13 for low-temperature NO adsorption

H Zhao, X Chen, AJ Hill, G Jing, Y Li… - Chemical Engineering …, 2023 - Elsevier
Pd/SSZ-13 catalysts were investigated for the simultaneous storage of NO and C 3 H 6 at
100° C. The effects of the state of Pd species on co-adsorption and release were studied …

Effects of alkali and alkaline earth metals on the activity and stability of Pd/SSZ-13 for passive NOx adsorption

D Li, Q Ding, Y Meng, Y Guo, L Pang, T Li - Separation and Purification …, 2023 - Elsevier
Pd/SSZ-13 has been proposed as a passive NO x adsorber (PNA) to effectively alleviate NO
x emission during vehicle cold start. However, the chemical poisons which are derived from …

The influence of phosphorus and CO poisoning on Pd/SSZ-13 with different Al distributions as passive NOx adsorbers

Y Wang, J Feng, T Chen, X Zhao, R Zhan… - Separation and Purification …, 2024 - Elsevier
Phosphorus and CO are typical poisonous substances under realistic working conditions for
Pd/SSZ-13 passive NOx Adsorbers (PNA). In this research, the Pd/SSZ-13 with different Al …

Unusual water-assisted NO adsorption over Pd/FER calcined at high temperatures: The effect of cation migration

I Song, K Khivantsev, Y Wu, M Bowden, Y Wang… - Applied Catalysis B …, 2022 - Elsevier
Moisture contained in vehicle exhaust gas normally degrades the capacity and efficiency of
Pd ion-exchanged zeolites as NO x adsorbents by competitive adsorption on active sites …