Challenges and recent advances in high capacity Li‐rich cathode materials for high energy density lithium‐ion batteries

W He, W Guo, H Wu, L Lin, Q Liu, X Han… - Advanced …, 2021 - Wiley Online Library
Li‐rich cathode materials have attracted increasing attention because of their high reversible
discharge capacity (> 250 mA hg− 1), which originates from transition metal (TM) ion redox …

Oxide cathodes: functions, instabilities, self healing, and degradation mitigations

Y Dong, J Li - Chemical Reviews, 2022 - ACS Publications
Recent progress in high-energy-density oxide cathodes for lithium-ion batteries has pushed
the limits of lithium usage and accessible redox couples. It often invokes hybrid anion-and …

[PDF][PDF] Progress on modification strategies of layered lithium-rich cathode materials for high energy lithium-ion batteries

H Lu, R Hou, S Chu, H Zhou, S Guo - Acta Phys.-Chim. Sin, 2023 - whxb.pku.edu.cn
High-performance rechargeable lithium-ion batteries have been widely used in portable
electronic devices, electric vehicles and other fields of electrochemical energy storage …

[HTML][HTML] Origin and regulation of oxygen redox instability in high-voltage battery cathodes

X Liu, GL Xu, VSC Kolluru, C Zhao, Q Li, X Zhou, Y Liu… - Nature Energy, 2022 - nature.com
Oxygen redox at high voltage has emerged as a transformative paradigm for high-energy
battery cathodes such as layered transition-metal oxides by offering extra capacity beyond …

Cation-disordered rocksalt transition metal oxides and oxyfluorides for high energy lithium-ion cathodes

RJ Clément, Z Lun, G Ceder - Energy & Environmental Science, 2020 - pubs.rsc.org
For lithium-ion rechargeable batteries to meet society's ever-growing demands in electrical
energy storage, eg for the electrification of transportation, for portable electronics and for grid …

[HTML][HTML] Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes

D Eum, B Kim, SJ Kim, H Park, J Wu, SP Cho, G Yoon… - Nature Materials, 2020 - nature.com
Despite the high energy density of lithium-rich layered-oxide electrodes, their real-world
implementation in batteries is hindered by the substantial voltage decay on cycling. This …

[HTML][HTML] Unified picture of anionic redox in Li/Na-ion batteries

M Ben Yahia, J Vergnet, M Saubanère, ML Doublet - Nature materials, 2019 - nature.com
Anionic redox in Li-rich and Na-rich transition metal oxides (A-rich-TMOs) has emerged as a
new paradigm to increase the energy density of rechargeable batteries. Ever since …

[HTML][HTML] Injection of oxygen vacancies in the bulk lattice of layered cathodes

P Yan, J Zheng, ZK Tang, A Devaraj, G Chen… - Nature …, 2019 - nature.com
Surfaces, interfaces and grain boundaries are classically known to be sinks of defects
generated within the bulk lattice. Here, we report an inverse case by which the defects …

[HTML][HTML] Persistent and partially mobile oxygen vacancies in Li-rich layered oxides

PM Csernica, SS Kalirai, WE Gent, K Lim, YS Yu, Y Liu… - Nature Energy, 2021 - nature.com
Increasing the energy density of layered oxide battery electrodes is challenging as
accessing high states of delithiation often triggers voltage degradation and oxygen release …

Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides

WE Gent, K Lim, Y Liang, Q Li, T Barnes, SJ Ahn… - Nature …, 2017 - nature.com
Lithium-rich layered transition metal oxide positive electrodes offer access to anion redox at
high potentials, thereby promising high energy densities for lithium-ion batteries. However …