Challenges and recent advances in high capacity Li‐rich cathode materials for high energy density lithium‐ion batteries
W He, W Guo, H Wu, L Lin, Q Liu, X Han… - Advanced …, 2021 - Wiley Online Library
Li‐rich cathode materials have attracted increasing attention because of their high reversible
discharge capacity (> 250 mA hg− 1), which originates from transition metal (TM) ion redox …
discharge capacity (> 250 mA hg− 1), which originates from transition metal (TM) ion redox …
Oxide cathodes: functions, instabilities, self healing, and degradation mitigations
Recent progress in high-energy-density oxide cathodes for lithium-ion batteries has pushed
the limits of lithium usage and accessible redox couples. It often invokes hybrid anion-and …
the limits of lithium usage and accessible redox couples. It often invokes hybrid anion-and …
[PDF][PDF] Progress on modification strategies of layered lithium-rich cathode materials for high energy lithium-ion batteries
H Lu, R Hou, S Chu, H Zhou, S Guo - Acta Phys.-Chim. Sin, 2023 - whxb.pku.edu.cn
High-performance rechargeable lithium-ion batteries have been widely used in portable
electronic devices, electric vehicles and other fields of electrochemical energy storage …
electronic devices, electric vehicles and other fields of electrochemical energy storage …
[HTML][HTML] Origin and regulation of oxygen redox instability in high-voltage battery cathodes
Oxygen redox at high voltage has emerged as a transformative paradigm for high-energy
battery cathodes such as layered transition-metal oxides by offering extra capacity beyond …
battery cathodes such as layered transition-metal oxides by offering extra capacity beyond …
Cation-disordered rocksalt transition metal oxides and oxyfluorides for high energy lithium-ion cathodes
For lithium-ion rechargeable batteries to meet society's ever-growing demands in electrical
energy storage, eg for the electrification of transportation, for portable electronics and for grid …
energy storage, eg for the electrification of transportation, for portable electronics and for grid …
[HTML][HTML] Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes
Despite the high energy density of lithium-rich layered-oxide electrodes, their real-world
implementation in batteries is hindered by the substantial voltage decay on cycling. This …
implementation in batteries is hindered by the substantial voltage decay on cycling. This …
[HTML][HTML] Unified picture of anionic redox in Li/Na-ion batteries
Anionic redox in Li-rich and Na-rich transition metal oxides (A-rich-TMOs) has emerged as a
new paradigm to increase the energy density of rechargeable batteries. Ever since …
new paradigm to increase the energy density of rechargeable batteries. Ever since …
[HTML][HTML] Injection of oxygen vacancies in the bulk lattice of layered cathodes
Surfaces, interfaces and grain boundaries are classically known to be sinks of defects
generated within the bulk lattice. Here, we report an inverse case by which the defects …
generated within the bulk lattice. Here, we report an inverse case by which the defects …
[HTML][HTML] Persistent and partially mobile oxygen vacancies in Li-rich layered oxides
Increasing the energy density of layered oxide battery electrodes is challenging as
accessing high states of delithiation often triggers voltage degradation and oxygen release …
accessing high states of delithiation often triggers voltage degradation and oxygen release …
Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides
Lithium-rich layered transition metal oxide positive electrodes offer access to anion redox at
high potentials, thereby promising high energy densities for lithium-ion batteries. However …
high potentials, thereby promising high energy densities for lithium-ion batteries. However …