Excited (triplet) states offer a myriad of attractive synthetic pathways, including
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …

The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Covalent organic frameworks (COFs) are promising hosts in heterogeneous catalysis.
Herein, we report a dual metalation strategy in a single two-dimensional-COF TpBpy for …

Abstract β-Amino acids are frequently found as important components in numerous
biologically active molecules, drugs and natural products. In particular, they are broadly …

Covalent organic frameworks (COFs) have received broad interest owing to their permanent
porosity, high stability, and tunable functionalities. COFs with long‐range π‐conjugation and …

The combined use of reaction kinetic analysis, ultrafast spectroscopy, and stoichiometric
organometallic studies has enabled the elucidation of the mechanistic underpinnings to a …

Aryl amination is an essential transformation for medicinal, process, and materials chemistry.
In addition to classic Buchwald–Hartwig amination conditions, blue-light-driven …

The formation of C‐heteroatom bonds represents an important type of bond‐forming
reaction in organic synthesis and often provides a fast and efficient access to privileged …

Synthetic organic chemistry has seen major advances due to the merger of nickel and
photoredox catalysis. A growing number of Ni-photoredox reactions are proposed to involve …