Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Optimizing the electrocatalytic selectivity of carbon dioxide reduction reaction by regulating the electronic structure of single‐atom M‐N‐C materials
T Tang, Z Wang, J Guan - Advanced Functional Materials, 2022 - Wiley Online Library
Electrochemical carbon dioxide reduction reaction (CO2RR) is an efficient strategy to relieve
global environmental and energy issues by converting excess CO2 from the atmosphere to …
global environmental and energy issues by converting excess CO2 from the atmosphere to …
Continuous Modulation of Electrocatalytic Oxygen Reduction Activities of Single‐Atom Catalysts through p‐n Junction Rectification
Fine‐tuning single‐atom catalysts (SACs) to surpass their activity limit remains challenging
at their atomic scale. Herein, we exploit p‐type semiconducting character of SACs having a …
at their atomic scale. Herein, we exploit p‐type semiconducting character of SACs having a …
Recent advances in electrocatalysis with phthalocyanines
S Yang, Y Yu, X Gao, Z Zhang, F Wang - Chemical Society Reviews, 2021 - pubs.rsc.org
Applications of phthalocyanines (Pcs) in electrocatalysis—including the oxygen reduction
reaction (ORR), the carbon dioxide reduction reaction (CO2RR), the oxygen evolution …
reaction (ORR), the carbon dioxide reduction reaction (CO2RR), the oxygen evolution …
Advanced electrocatalysts with single-metal-atom active sites
Electrocatalysts with single metal atoms as active sites have received increasing attention
owing to their high atomic utilization efficiency and exotic catalytic activity and selectivity …
owing to their high atomic utilization efficiency and exotic catalytic activity and selectivity …
An adjacent atomic platinum site enables single‐atom iron with high oxygen reduction reaction performance
The modulation effect has been widely investigated to tune the electronic state of single‐
atomic M‐N‐C catalysts to enhance the activity of oxygen reduction reaction (ORR) …
atomic M‐N‐C catalysts to enhance the activity of oxygen reduction reaction (ORR) …
Atomic‐level modulation of electronic density at cobalt single‐atom sites derived from metal–organic frameworks: enhanced oxygen reduction performance
Demonstrated here is the correlation between atomic configuration induced electronic
density of single‐atom Co active sites and oxygen reduction reaction (ORR) performance by …
density of single‐atom Co active sites and oxygen reduction reaction (ORR) performance by …
Iron phthalocyanine with coordination induced electronic localization to boost oxygen reduction reaction
K Chen, K Liu, P An, H Li, Y Lin, J Hu, C Jia, J Fu… - Nature …, 2020 - nature.com
Iron phthalocyanine (FePc) is a promising non-precious catalyst for the oxygen reduction
reaction (ORR). Unfortunately, FePc with plane-symmetric FeN4 site usually exhibits an …
reaction (ORR). Unfortunately, FePc with plane-symmetric FeN4 site usually exhibits an …
Surface coordination chemistry of atomically dispersed metal catalysts
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …
catalysts, have been widely investigated during the past two decades. The atomic dispersion …
Asymmetric N, P‐Coordinated Single‐Atomic Fe Sites with Fe2P Nanoclusters/Nanoparticles on Porous Carbon Nanosheets for Highly Efficient Oxygen …
H Liu, L Jiang, Y Sun, J Khan, B Feng… - Advanced Energy …, 2023 - Wiley Online Library
Disrupting the symmetrical electron distribution of single‐atomic Fe sites is proposed as an
effective strategy for improving the intrinsic activity in the oxygen reduction reaction (ORR) …
effective strategy for improving the intrinsic activity in the oxygen reduction reaction (ORR) …