Advanced functional liquid crystals

J Uchida, B Soberats, M Gupta, T Kato - Advanced Materials, 2022 - Wiley Online Library
Liquid crystals have been intensively studied as functional materials. Recently, integration of
various disciplines has led to new directions in the design of functional liquid‐crystalline …

Spontaneous deracemizations

T Buhse, JM Cruz, ME Noble-Teran… - Chemical …, 2021 - ACS Publications
Spontaneous deracemizations is a challenging, multidisciplinary subject in current chirality
research. In the absence of any chiral inductors, an achiral substance or a racemic …

[HTML][HTML] Hierarchical self-assembly into chiral nanostructures

Y Sang, M Liu - Chemical Science, 2022 - pubs.rsc.org
One basic principle regulating self-assembly is associated with the asymmetry of constituent
building blocks or packing models. Using asymmetry to manipulate molecular-level devices …

[HTML][HTML] Spontaneous symmetry breaking in polar fluids

CJ Gibb, J Hobbs, DI Nikolova, T Raistrick… - Nature …, 2024 - nature.com
Spontaneous symmetry breaking and emergent polar order are each of fundamental
importance to a range of scientific disciplines, as well as generating rich phase behaviour in …

Symmetry breaking in the supramolecular gels of an achiral gelator exclusively driven by π–π stacking

Z Shen, Y Jiang, T Wang, M Liu - Journal of the American …, 2015 - ACS Publications
Supramolecular symmetry breaking, in which chiral assemblies with imbalanced right-and
left-handedness emerge from achiral molecular building blocks, has been achieved in the …

[HTML][HTML] Multi-level chirality in liquid crystals formed by achiral molecules

M Salamończyk, N Vaupotič, D Pociecha… - Nature …, 2019 - nature.com
Complex materials often exhibit a hierarchical structure with an intriguing mechanism
responsible for the 'propagation'of order from the molecular to the nano-or micro-scale level …

Mirror symmetry breaking by chirality synchronisation in liquids and liquid crystals of achiral molecules

C Tschierske, G Ungar - ChemPhysChem, 2016 - Wiley Online Library
Spontaneous mirror symmetry breaking is an efficient way to obtain homogeneously chiral
agents, pharmaceutical ingredients and materials. It is also in the focus of the discussion …

Mirror symmetry breaking in liquids and liquid crystals

C Tschierske - Liquid Crystals, 2018 - Taylor & Francis
In the recent two decades liquid crystal science has contributed significantly to the
understanding of mirror symmetry breaking and spontaneous emergence of chirality in …

Enantiomers Self-Sort into Separate Counter-Twisted Ribbons of the Fddd Liquid Crystal─Antiferrochirality and Parachirality

Y Wang, YX Li, L Cseh, YX Chen… - Journal of the …, 2023 - ACS Publications
The recently discovered orthorhombic liquid crystal (LC) phase of symmetry Fddd is proving
to be widespread. In this work, a chiral hydroxybutyrate linkage is inserted into the molecular …

Chiral Superstructure Mesophases of Achiral Bent‐Shaped Molecules–Hierarchical Chirality Amplification and Physical Properties

KV Le, H Takezoe, F Araoka - Advanced Materials, 2017 - Wiley Online Library
Chiral mesophases in achiral bent‐shaped molecules have attracted particular attention
since their discovery in the middle 1990s, not only because of their homochirality and …