Catalytic strategies and mechanism analysis orbiting the center of critical intermediates in lignin depolymerization
Lignin, as a precious resource given to mankind by nature with abundant functional aromatic
structures, has drawn much attention in the recent decade from academia to industry …
structures, has drawn much attention in the recent decade from academia to industry …
Carbon–Carbon Bond Cleavage for Late-Stage Functionalization
YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …
Transition-metal-free synthesis of pyrimidines from lignin β-O-4 segments via a one-pot multi-component reaction
Heteroatom-participated lignin depolymerization for heterocyclic aromatic compounds
production is of great importance to expanding the product portfolio and meeting value …
production is of great importance to expanding the product portfolio and meeting value …
Towards bioresource-based aggregation-induced emission luminogens from lignin β-O-4 motifs as renewable resources
T Guo, Y Lin, D Pan, X Zhang, W Zhu, XM Cai… - Nature …, 2023 - nature.com
One-pot synthesis of heterocyclic aromatics with good optical properties from phenolic β-O-4
lignin segments is of high importance to meet high value added biorefinery demands …
lignin segments is of high importance to meet high value added biorefinery demands …
Catalytic scissoring of lignin into aryl monomers
M Wang, F Wang - Advanced Materials, 2019 - Wiley Online Library
Lignin is an aromatic polymer, which is the biggest and most sustainable reservoir for
aromatics. The selective conversion of lignin polymers into aryl monomers is a promising …
aromatics. The selective conversion of lignin polymers into aryl monomers is a promising …
Selective upcycling of polyolefins into high-value nitrogenated chemicals
B Zhao, Z Hu, Y Sun, R Hajiayi, T Wang… - Journal of the American …, 2024 - ACS Publications
The selective upcycling of polyolefins to create products of increased value has emerged as
an innovative approach to carbon resource stewardship, drawing significant scientific and …
an innovative approach to carbon resource stewardship, drawing significant scientific and …
Metal-free, redox-neutral, site-selective access to heteroarylamine via direct radical–radical cross-coupling powered by visible light photocatalysis
Transition-metal-catalyzed C–N bond-forming reactions have emerged as fundamental and
powerful tools to construct arylamines, a common structure found in drug agents, natural …
powerful tools to construct arylamines, a common structure found in drug agents, natural …
Cleaving arene rings for acyclic alkenylnitrile synthesis
Synthetic chemistry is built around the formation of carbon–carbon bonds. However, the
development of methods for selective carbon–carbon bond cleavage is a largely unmet …
development of methods for selective carbon–carbon bond cleavage is a largely unmet …
Engineering single–atom active sites anchored covalent organic frameworks for efficient metallaphotoredox CN cross–coupling reactions
Photoredox catalysis has become an indispensable solution for the synthesis of small
organic molecules. However, the precise construction of single-atomic active sites not only …
organic molecules. However, the precise construction of single-atomic active sites not only …
Aminodealkenylation: Ozonolysis and copper catalysis convert C(sp3)–C(sp2) bonds to C(sp3)–N bonds
Great efforts have been directed toward alkene π bond amination. In contrast, analogous
functionalization of the adjacent C (sp3)–C (sp2) σ bonds is much rarer. Here we report how …
functionalization of the adjacent C (sp3)–C (sp2) σ bonds is much rarer. Here we report how …