The recent advances in the N‐heterocyclic carbene (NHC)‐organocatalyzed generation of
azolium enolate intermediates and their subsequent interception with electrophiles are …

Over the past decade, the catalysis of N-heterocyclic carbenes has achieved significant
advances. In this area, aldehydes, enals, and esters, are commonly employed as starting …

Over the recent decades, due to the special electronic characteristics and diverse
reactivities, N‐heterocyclic carbene (NHC) has received significant interest in …

The activation of an ester by N-heterocyclic carbene (NHC) organocatalysis is an efficient
and important approach for generating an NHC-bound enolate intermediate, an important …

The use of functionalized aldimines has been demonstrated as newly structural 1, 4‐dipole
precursors under carbene catalysis. More importantly, enantiodivergent organocatalysis has …

In this study, the mechanism and origin of the stereoselectivity of an N-heterocyclic carbene
(NHC)-catalyzed transformation reaction between an enal and a β-silyl enone are …

An effective and economical acid-promoted three-component reaction for the construction of
C–P and C–C bonds for the synthesis of γ-ketophosphine oxides with water as the only …

A new and unprecedented stereoselective synthetic approach to δ-oxoesters derivatives
from readily available starting materials has been developed. This method, catalyzed by N …

The catalytic generation of C (1)‐ammonium enolates from the corresponding α‐silyl‐α‐alkyl
substituted carboxylic acids using the isothiourea HyperBTM is reported. This desilylative …

Herein, we have designed heterocycle-based ligands having chalcone appended triazole
silane in the scaffold by using a cost-effective and simple synthetic procedure. They were …