The miniaturization of components used in the construction of working devices is being
pursued currently by the large‐downward (top‐down) fabrication. This approach, however …

Abstract Die zum Bau kleiner Maschinen notwendige Miniaturisierung von Komponenten
erfolgt derzeit nach dem Verkleinerungsprinzip (top‐down approach). Diesem Ansatz, der …

We implemented isosteric replacement of sulfur to selenium in a novel thiosemicarbazone
(PPTP4c4mT) to create a selenosemicarbazone (PPTP4c4mSe) that demonstrates …

Changing the oxidation state of redox‐active ligands is a powerful method for
electrochemically controlling the reactivity and selectivity of bound transition metals (see …

A tripodal cyclotriveratrylene-based ligand with chelating 2, 2 '-bipyridine arms self-
assembles with either Zn (NO3) 2 or Co (NO3) 2 to give 3-D trigonal bipyramidal [M3L2] …

Efficient metal-based chiroptical switches have been designed that are capable of achieving
multiple stable and reversible states. Studies in this field have yielded a variety of complex …

Recently we have demonstrated a series of systems in which complex structures were
created from simple amine and aldehyde subcomponents by copper (I)‐templated imine …

Fast spinning motion is observed in a copper (i) rotaxane. This “motor‐like” molecule
consists of an axle, bearing two bulky stoppers at its ends, and a ring containing two …

This Letter demonstrates the molecular design of novel self-assembled chiral cryptophanes.
Mediated by square-planar Pd (II) complexes, racemic pyridyl cyclotriveratrylene derivative …

Intense chiroptical properties and efficient reversibility of the chemical redox cycle support
the adaptability of the CuI/CuII complex system 1/2 for the development of a binary …