This article reviews the history and the current state of knowledge concerning the ability of
the heavy chalcogen atoms S and Se, and to some extent Te, to participate in a H-bond as …

London dispersion, universally attractive forces originating from fluctuating dipoles, is
omnipresent in molecules. While its understanding has recently made tremendous progress …

We present the CHAL336 benchmark set—the most comprehensive database for the
assessment of chalcogen-bonding (CB) interactions. After careful selection of suitable …

The synthesis and structural characterization of a series of supramolecular complexes of
bicyclic cationic pyridine-fused 1, 2, 4-selenodiazoles with various anions is reported. The …

The mechanochemical syntheses of allyl and indenyl palladate complexes are reported. All
compounds were obtained in quantitative yields and microanalytically pure without the need …

The stability of hybrid organic–inorganic halide perovskite semiconductors remains a
significant obstacle to their application in photovoltaics. To this end, the use of low …

The series of substituted 1, 2, 4-selenodiazolium tetraphenylborate complexes were
synthesized via cyclization between 2-pyridylselenylchloride, followed by the anion …

In this manuscript the ability of selenium carbohydrates to undergo chalcogen bonding
(ChB) interactions with protein residues has been studied at the RI-MP2/def2-TZVP level of …

Chalcogenodiazoles have been intensively studied in recent years in the context of their
supramolecular chemistry. In contrast, the newly discovered cationic 1, 2, 4-selenodiazole …

We have performed a hierarchical ab initio benchmark and DFT performance study of
D2Ch••• A− chalcogen bonds (Ch= S, Se; D, A= F, Cl). The ab initio benchmark study is …