The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

The metal‐catalyzed hydroboration reaction provides access to functionalized organoboron
derivatives that cannot be easily prepared using traditional reagents. New developments in …

Mesitaldehyde reacts cleanly with (IPr) CuB (pin)[IPr= 1, 3-bis (2, 6-diisopropylphenyl)
imidazol-2-ylidene); pin= 2, 3-dimethyl-2, 3-butanediolate] to afford the product complex 1 …

Bis (boronate) compounds have been attracting much attention as versatile building blocks
for concise synthesis of complex molecules because these compounds enable multiple C–C …

A deoxygenative gem-diborylation and gem-silylborylation of aldehydes and ketones is
described. The key for the success of this transformation is the base-promoted C–O bond …

Direct C (sp3)–H borylation of amides, ureas, and 2-aminopyridine derivatives at the
position α to the N atom, which gives the corresponding α-aminoalkylboronates, has been …

In this feature article, we discuss selected recent aspects of metal boryl (M–BR2) chemistry
pertaining, in particular, to the role of late and post-transition metal boryl complexes in …

Among the most significant advances in organic synthesis over the past few decades are
those associated with the development of transition metal complexes for their use as …

The detailed mechanism for the diboration of aldehydes catalyzed by (NHC) Cu (boryl)
complexes (NHC= N-heterocyclic carbene) was studied with the aid of DFT by calculating …