Synthesis of 3d Metallic Single-Molecule Magnets

G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry

A Escuer, J Esteban, SP Perlepes… - Coordination Chemistry …, 2014 - Elsevier
The chemistry of the azido-bridged coordination clusters continues to attract the intense
interest of synthetic inorganic chemists and scientists working in the interdisciplinary field of …

Azide as a bridging ligand and magnetic coupler in transition metal clusters

A Escuer, G Aromí - European journal of inorganic chemistry, 2006 - Wiley Online Library
The synthesis of transition metal spin‐clusters has become an important sub‐discipline of
coordination chemistry, especially since the discovery of single‐molecule magnets (SMMs) …

Using tripodal alcohols to build high-spin molecules and single-molecule magnets

EK Brechin - Chemical communications, 2005 - pubs.rsc.org
Using tripodal alcohols to build high-spin molecules and single-molecule magnets - Chemical
Communications (RSC Publishing) DOI:10.1039/B510102F Royal Society of Chemistry View …

Functionalization of polyoxometalates by carboxylato and azido ligands: macromolecular complexes and extended compounds

P Mialane, A Dolbecq, F Sécheresse - Chemical communications, 2006 - pubs.rsc.org
Polyoxometalate compounds continue to be widely studied due to their relevance in various
fields such as catalysis or magnetochemistry. In this article, we will focus on two topics we …

Coordination Polymers with End-On Azido and Pyridine Carboxylate N-Oxide Bridges Displaying Long-Range Magnetic Ordering with Low Dimensional Character

Z He, ZM Wang, S Gao, CH Yan - Inorganic chemistry, 2006 - ACS Publications
A series of 2D and one 3D transition-metal− azido coordination polymers with pyridine
carboxylate N-oxide, isonicotinate N-oxide (INO), and nicotinate N-oxide (NNO) as the …

What Controls the Magnetic Interaction in bis‐μ‐Alkoxo MnIII Dimers? A Combined Experimental and Theoretical Exploration

N Berg, T Rajeshkumar, SM Taylor… - … A European Journal, 2012 - Wiley Online Library
The synthesis and magnetic characterisation of a series of bis‐μ‐alkoxide bridged MnIII
dinuclear complexes of general formula [MnIII2 (μ‐OR) 2 (biphen) 2 (ROH) x (L) y](where R …

Hydrothermal synthesis, structures, and physical properties of four new flexible multicarboxylate ligands-based compounds

Z Pan, H Zheng, T Wang, Y Song, Y Li, Z Guo… - Inorganic …, 2008 - ACS Publications
Four new compounds of partially or wholly deprotonated 5, 5′-(1, 4-phenylenebis
(methylene)) bis (oxy) diisophthalic acid (H4L1) and 5, 5′-(1, 3-phenylenebis (methylene)) …

Structural and Magnetic Properties of MnIII and CuII Tetranuclear Azido Polyoxometalate Complexes: Multifrequency High‐Field EPR Spectroscopy of Cu4 Clusters with S=1 …

P Mialane, C Duboc, J Marrot, E Rivière… - … A European Journal, 2006 - Wiley Online Library
Two new azido‐bridged polyoxometalate compounds were synthesized in
acetonitrile/methanol media and their molecular structures have been determined by X‐ray …

Slow magnetic relaxation in hexacoordinated cobalt (II) field-induced single-ion magnets

A Świtlicka, B Machura, M Penkala, A Bieńko… - Inorganic Chemistry …, 2020 - pubs.rsc.org
To gain a better insight into the factors affecting the enhancement of the energy barrier in
single molecule (single ion) magnets, three hexacoordinate cobalt (II) complexes based on …