Research and industrial interest in radical C–H activation/radical cross-coupling chemistry
has continuously grown over the past few decades. These reactions offer fascinating and …

Vinyl azides are highly versatile synthons that provide access to numerous N-heterocycles
and other functional groups. α-Substituted vinyl azides (azido vinylidenes) are a special …

Natural product-inspired compound collections serve as excellent sources for the
identification of new bioactive compounds to treat disease. However, such compounds must …

Among organic azides, vinyl azides have attracted significant attention, because of their
unique properties in organic synthesis, which led to reports of many types of research on this …

An N-heterocyclic carbene (NHC)–copper complex supported on hypercrosslinked polymers
(HCPs) was successfully synthesized through a simple external cross-linking reaction. The …

Transition metal-free oxidative coupling of vinyl azides with sulfonyl hydrazines is described.
This radical process realized oxidative multi-functionalization of vinyl azides in the presence …

Pyrroles are important synthetic targets as a result of their occurrence in numerous
biologically active molecules, their important roles in diverse living processes, and their …

Direct aerobic oxidative cross-dehydrogenative coupling of aryl acetaldehydes at C-3
position of imidazoheterocycles via copper catalyzed reaction resulted in the synthesis of …

Palladium-catalyzed site-selective dearomative C2-arylation of 2, 5-diaryl-1 H-pyrroles with
aryl chlorides was accomplished, and a series of 2, 2, 5-triaryl-2 H-pyrroles were …

Mn III-catalyzed functionalization of vinyl azides via phosphorylation was developed to
synthesize various β-keto phosphine oxides in high yields. The transformation is operated in …