Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Raman spectroscopy, an ideal tool for studying the physical properties and applications of metal–organic frameworks (MOFs)

J Sunil, C Narayana, G Kumari… - Chemical Society …, 2023 - pubs.rsc.org
Metal–organic frameworks (MOFs) are a unique family of materials constructed by
coordinating metal ions or clusters to bridging organic ligands. Many of these materials are …

Linker functionalized metal-organic frameworks

SAA Razavi, A Morsali - Coordination chemistry reviews, 2019 - Elsevier
Owing to their three dimensionality and high porosity, metal-organic frameworks (MOFs)
have attracted the attention of scientists especially chemists and material engineers. The …

A Triazole-Containing Metal–Organic Framework as a Highly Effective and Substrate Size-Dependent Catalyst for CO2 Conversion

PZ Li, XJ Wang, J Liu, JS Lim, R Zou… - Journal of the American …, 2016 - ACS Publications
A highly porous metal–organic framework (MOF) incorporating both exposed metal sites and
nitrogen-rich triazole groups was successfully constructed via solvothermal assembly of a …

Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies

P Deria, JE Mondloch, E Tylianakis… - Journal of the …, 2013 - ACS Publications
A new functionalization technique, s olvent-a ssisted l igand i ncorporation (SALI), was
developed to efficiently incorporate carboxylate-based functionalities in the Zr-based metal …

Multi-dimensional metal-organic frameworks based on mixed linkers: Interplay between structural flexibility and functionality

S Bhattacharyya, TK Maji - Coordination Chemistry Reviews, 2022 - Elsevier
Metal-organic frameworks (MOFs) are regarded widely because of their intriguing structural
dynamism, which sets them apart from other porous materials. Such structural flexibility or …

Temperature induced structural transformations and gas adsorption in the zeolitic imidazolate framework ZIF-8: A Raman study

G Kumari, K Jayaramulu, TK Maji… - The Journal of Physical …, 2013 - ACS Publications
Here we have used Raman spectroscopy to investigate molecular level changes in the
zeolitic imidazolate framework ZIF-8 (a prototypical zeolite-like porous metal organic …

Highly Effective Carbon Fixation via Catalytic Conversion of CO2 by an Acylamide-Containing Metal–Organic Framework

PZ Li, XJ Wang, J Liu, HS Phang, Y Li… - Chemistry of …, 2017 - ACS Publications
On the way toward a sustainable low-carbon future, in addition to physical capture and
permanent underground deposition of anthropogenic emitted CO2, an alternative and very …

Elucidating the breathing of the metal–organic framework MIL-53 (Sc) with ab initio molecular dynamics simulations and in situ X-ray powder diffraction experiments

L Chen, JPS Mowat, D Fairen-Jimenez… - Journal of the …, 2013 - ACS Publications
Ab initio molecular dynamics (AIMD) simulations have been used to predict structural
transitions of the breathing metal–organic framework (MOF) MIL-53 (Sc) in response to …

[HTML][HTML] Effect of ring rotation upon gas adsorption in SIFSIX-3-M (M= Fe, Ni) pillared square grid networks

SK Elsaidi, MH Mohamed, CM Simon, E Braun… - Chemical …, 2017 - pubs.rsc.org
Dynamic and flexible metal–organic frameworks (MOFs) that respond to external stimuli,
such as stress, light, heat, and the presence of guest molecules, hold promise for …