Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

A new carbon allotrope: graphdiyne

Z Zheng, Y Xue, Y Li - Trends in Chemistry, 2022 - cell.com
Graphdiyne (GDY) represents a new trending class of carbon materials demonstrating
significant advantages in many areas such as energy, catalysis, photoelectricity, and …

Synthesis of a Porous [14] Annulene Graphene Nanoribbon and a Porous [30] Annulene Graphene Nanosheet on Metal Surfaces

T Qin, D Guo, J Xiong, X Li, L Hu… - Angewandte Chemie …, 2023 - Wiley Online Library
The electrical and mechanical properties of graphene‐based materials can be tuned by the
introduction of nanopores, which are sensitively related to the size, morphology, density, and …

Enantioselective difunctionalization of alkenes by a palladium‐catalyzed heck/sonogashira sequence

L Zhou, S Li, B Xu, D Ji, L Wu, Y Liu… - Angewandte Chemie …, 2020 - Wiley Online Library
Sonogashira‐type cross‐couplings are one of the most significant alkynylations in organic
chemistry. One of the first palladium‐catalyzed intramolecular Heck/Sonogashira reactions …

Controllable synthesis of graphdiyne nanoribbons

W Zhou, H Shen, Y Zeng, Y Yi, Z Zuo… - Angewandte Chemie …, 2020 - Wiley Online Library
Graphdiyne nanoribbons with high chemical precision are of great significance for further
understanding of the intrinsic properties of graphdiyne and the relationship between …

Chemisorption-induced formation of biphenylene dimer on Ag (111)

Z Zeng, D Guo, T Wang, Q Chen, A Matěj… - Journal of the …, 2021 - ACS Publications
We report an example that demonstrates the clear interdependence between surface-
supported reactions and molecular-adsorption configurations. Two biphenyl-based …

Confined on-surface organic synthesis: Strategies and mechanisms

T Wang, J Zhu - Surface Science Reports, 2019 - Elsevier
On-surface synthesis has been one of the hottest research fields in surface science in the
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …

Steering On-Surface Reactions by Kinetic and Thermodynamic Strategies

T Wang, Q Fan, J Zhu - The Journal of Physical Chemistry Letters, 2023 - ACS Publications
On-surface synthesis has emerged as a powerful tool to fabricate various functional low-
dimensional nanostructures with atomic precision, thus becoming a promising platform for …

Real-time imaging of on-surface Ullmann polymerization reveals an inhibiting effect of adatoms

D Dettmann, M Panighel… - Journal of the …, 2024 - ACS Publications
Ullmann coupling is a widely used reaction for the on-surface growth of low-dimensional
carbon nanomaterials. The irreversible nature of this reaction prevents the “self-healing” of …

Enantioselective palladium/copper-catalyzed C–C σ-bond activation synergized with Sonogashira-type C (sp 3)–C (sp) cross-coupling alkynylation

FN Sun, WC Yang, XB Chen, YL Sun, J Cao, Z Xu… - Chemical …, 2019 - pubs.rsc.org
The Sonogashira-type cross-coupling reaction is one of the most significant alkynylation
transformations in organic chemistry. However, highly enantioselective alkynylation via the …