Intermolecular Diels-Alder cycloadditions of furfural-based chemicals from renewable resources: a focus on the regio-and diastereoselectivity in the reaction with …
KI Galkin, VP Ananikov - International Journal of Molecular Sciences, 2021 - mdpi.com
A recent strong trend toward green and sustainable chemistry has promoted the intensive
use of renewable carbon sources for the production of polymers, biofuels, chemicals …
use of renewable carbon sources for the production of polymers, biofuels, chemicals …
Complex polymer architectures using ring-opening metathesis polymerization: synthesis, applications, and practical considerations
SE Blosch, SJ Scannelli, M Alaboalirat… - Macromolecules, 2022 - ACS Publications
Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …
and these observations have driven polymer scientists to synthesize complex architectures …
The Fluorocarbene Exploit: Enforcing Alternation in Ring-Opening Metathesis Polymerization
K Tashiro, M Akiyama, K Kashiwagi… - Journal of the American …, 2023 - ACS Publications
Fluoroalkenes are known to be notoriously reluctant substrates for olefin metathesis due to
the generation of thermodynamically stable Fischer-type fluorocarbene intermediates, which …
the generation of thermodynamically stable Fischer-type fluorocarbene intermediates, which …
Biomass-Derived Degradable Polymers via Alternating Ring-Opening Metathesis Polymerization of Exo-Oxanorbornenes and Cyclic Enol Ethers
Degradable polymers made via ring-opening metathesis polymerization (ROMP) hold
tremendous promise as eco-friendly materials. However, most of the ROMP monomers are …
tremendous promise as eco-friendly materials. However, most of the ROMP monomers are …
Diels–Alder Cycloadditions of Bio-Derived Furans with Maleimides as a Sustainable «Click» Approach towards Molecular, Macromolecular and Hybrid Systems
KI Galkin, IV Sandulenko, AV Polezhaev - Processes, 2021 - mdpi.com
This mini-review highlights the recent research trends in designing organic or organic-
inorganic hybrid molecular, biomolecular and macromolecular systems employing …
inorganic hybrid molecular, biomolecular and macromolecular systems employing …
Simple Monomers for Precise Polymer Functionalization During Ring-Opening Metathesis Polymerization
Controlling the monomer sequence of synthetic polymers is a grand challenge in polymer
science. Conventional sequence control has been achieved in dispersed polymers by …
science. Conventional sequence control has been achieved in dispersed polymers by …
Living Alternating Ring‐Opening Metathesis Copolymerization of 2, 3‐Dihydrofuran to Provide Completely Degradable Polymers
Dihydrofuran (DHF) has recently been gaining significant attention as a comonomer in
metathesis polymerization, thanks to its ability to provide the resultant polymer backbones …
metathesis polymerization, thanks to its ability to provide the resultant polymer backbones …
Cascade alternating metathesis cyclopolymerization of diynes and dihydrofuran
X Sui, WR Gutekunst - ACS macro letters, 2022 - ACS Publications
Ruthenium alkoxymethylidene complexes have recently come into view as competent
species for metathesis copolymerization reactions when coupled with appropriate …
species for metathesis copolymerization reactions when coupled with appropriate …
Chemically recyclable oxygen-protective polymers developed by ring-opening metathesis homopolymerization of cyclohexene derivatives
The ring-opening metathesis polymerization (ROMP) of six-membered cyclic olefins has
been a long-standing challenge due to their low ring strain energies (RSEs). Here, we …
been a long-standing challenge due to their low ring strain energies (RSEs). Here, we …
Controlled alternating metathesis copolymerization of terminal alkynes
Terminal alkynes display high reactivity toward Ru-carbene metathesis catalysts. However,
the formation of a less reactive bulky carbene hinders their homopolymerization …
the formation of a less reactive bulky carbene hinders their homopolymerization …