Intermolecular Diels-Alder cycloadditions of furfural-based chemicals from renewable resources: a focus on the regio-and diastereoselectivity in the reaction with …

KI Galkin, VP Ananikov - International Journal of Molecular Sciences, 2021 - mdpi.com
A recent strong trend toward green and sustainable chemistry has promoted the intensive
use of renewable carbon sources for the production of polymers, biofuels, chemicals …

Complex polymer architectures using ring-opening metathesis polymerization: synthesis, applications, and practical considerations

SE Blosch, SJ Scannelli, M Alaboalirat… - Macromolecules, 2022 - ACS Publications
Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …

The Fluorocarbene Exploit: Enforcing Alternation in Ring-Opening Metathesis Polymerization

K Tashiro, M Akiyama, K Kashiwagi… - Journal of the American …, 2023 - ACS Publications
Fluoroalkenes are known to be notoriously reluctant substrates for olefin metathesis due to
the generation of thermodynamically stable Fischer-type fluorocarbene intermediates, which …

Biomass-Derived Degradable Polymers via Alternating Ring-Opening Metathesis Polymerization of Exo-Oxanorbornenes and Cyclic Enol Ethers

H Sun, T Ibrahim, A Ritacco, K Durkee - ACS Macro Letters, 2023 - ACS Publications
Degradable polymers made via ring-opening metathesis polymerization (ROMP) hold
tremendous promise as eco-friendly materials. However, most of the ROMP monomers are …

Diels–Alder Cycloadditions of Bio-Derived Furans with Maleimides as a Sustainable «Click» Approach towards Molecular, Macromolecular and Hybrid Systems

KI Galkin, IV Sandulenko, AV Polezhaev - Processes, 2021 - mdpi.com
This mini-review highlights the recent research trends in designing organic or organic-
inorganic hybrid molecular, biomolecular and macromolecular systems employing …

Simple Monomers for Precise Polymer Functionalization During Ring-Opening Metathesis Polymerization

JC Foster, JT Damron, H Zhang - Macromolecules, 2023 - ACS Publications
Controlling the monomer sequence of synthetic polymers is a grand challenge in polymer
science. Conventional sequence control has been achieved in dispersed polymers by …

Living Alternating Ring‐Opening Metathesis Copolymerization of 2, 3‐Dihydrofuran to Provide Completely Degradable Polymers

T An, H Ryu, TL Choi - Angewandte Chemie, 2023 - Wiley Online Library
Dihydrofuran (DHF) has recently been gaining significant attention as a comonomer in
metathesis polymerization, thanks to its ability to provide the resultant polymer backbones …

Cascade alternating metathesis cyclopolymerization of diynes and dihydrofuran

X Sui, WR Gutekunst - ACS macro letters, 2022 - ACS Publications
Ruthenium alkoxymethylidene complexes have recently come into view as competent
species for metathesis copolymerization reactions when coupled with appropriate …

Chemically recyclable oxygen-protective polymers developed by ring-opening metathesis homopolymerization of cyclohexene derivatives

K Choi, SH Hong - Chem, 2023 - cell.com
The ring-opening metathesis polymerization (ROMP) of six-membered cyclic olefins has
been a long-standing challenge due to their low ring strain energies (RSEs). Here, we …

Controlled alternating metathesis copolymerization of terminal alkynes

S Pal, I Mandal, AFM Kilbinger - ACS Macro Letters, 2022 - ACS Publications
Terminal alkynes display high reactivity toward Ru-carbene metathesis catalysts. However,
the formation of a less reactive bulky carbene hinders their homopolymerization …