Abstract The regio‐, site‐, stereo‐or chemoselective homogeneous catalytic transformations
are extremely important for the growth/success of the current chemical industry. Based on …

Fluorinated carbenes take an important position in the synthesis of fluorine-containing
molecules in organic synthesis. When carbon centered carbenes are installed with fluorides …

The fluorinated entities are considered a privileged structure class in the field of medicinal
chemistry because of the amplified bioactivity they exhibit. In this regard, developments in C …

Herein, the density functional theory method was employed to investigate the mechanism of
the ligand-promoted divergent α, β-dehydrogenation of aliphatic acids. The calculated …

The mechanism of Pd (II)-catalyzed, mono-N-protected amino acid (MPAA) ligand and TBHP
oxidant-mediated lactonization of β-C (sp3)–H bond in aliphatic carboxylic acid has been …

The transition metal-catalysed dicarbofunctionalisation of unactivated alkenes normally
requires exogenous strong coordinated directing groups, thus reducing the overall reaction …

The mechanism of the Pd (II)-catalyzed, pyridine–pyridone ligand-enabled hydroxylation of
the C (sp2)–H bond in pyridine-4-carboxylic acid with molecular oxygen has been studied …

Nucleophilic aromatic substitution (SNAr) reactions of non-activated aryl fluorides with
amide enolates are reported. The reaction proceeds under relatively mild reaction …

Employing density functional theory (DFT) calculations, the study meticulously analyzes the
mechanistic details of the Pd-catalyzed dual-γ-1, 1-C (sp3)–H activation of aliphatic …

A nickel-catalysed reductive cross-coupling reaction between 2-bromo cycloalkenyl
carboxylic acids and alkyl bromides has been developed, affording all-carbon …