Indenofluorenes for organic optoelectronics: the dance of fused five-and six-membered rings enabling structural versatility

A Can, A Facchetti, H Usta - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
Polycyclic π-conjugated hydrocarbons (PCHs), either unfunctionalized or structurally
modified derivatives, have attracted tremendous interest in the past few decades as high …

Ladder‐Like Difluoroindacenodithiophene‐4, 9‐dione Derivative: A New Acceptor System for High‐Mobility n‐Type Polymer Semiconductors

X Tao, W Li, Q Wu, H Wei, Y Yan, L Zhao… - Advanced Functional …, 2023 - Wiley Online Library
Ladder‐like aromatic diketones (LADK), which possess a coplanar π‐extended geometry, a
high electron deficiency as well as various attractive optoelectronic properties, are …

[HTML][HTML] Indacenodibenzothiophenes: synthesis, optoelectronic properties and materials applications of molecules with strong antiaromatic character

JL Marshall, K Uchida, CK Frederickson, C Schütt… - Chemical …, 2016 - pubs.rsc.org
Indeno [1, 2-b] fluorenes (IFs), while containing 4n π-electrons, are best described as two
aromatic benzene rings fused to a weakly paratropic s-indacene core. In this study, we find …

Pentaleno[1,2-a:4,5′]diacenaphthylenes: Uniquely Stabilized Pentalene Derivatives

B Yuan, J Zhuang, KM Kirmess… - The Journal of …, 2016 - ACS Publications
We demonstrate the preparation of diacenaphthopentalene derivatives via a palladium-
catalyzed dimerization of 1-iodo-2-arylethynyl-acenaphthylenes. The resulting 7, 14 …

Donor/Acceptor Dihydroindeno[1,2‐a]fluorene and Dihydroindeno[2,1‐b]fluorene: Towards New Families of Organic Semiconductors

M Romain, D Tondelier, B Geffroy… - … A European Journal, 2015 - Wiley Online Library
New families of donor/acceptor semiconductors based on dihydroindeno [1, 2‐a] fluorene
and dihydroindeno [2, 1‐b] fluorene are reported. Due to the spiro bridges, this new …

Boosting the Charge Transport Property of Indeno [1, 2‐b] fluorene‐6, 12‐dione though Incorporation of Sulfur‐or Nitrogen‐Linked Side Chains

ZP Fan, XY Li, XE Luo, X Fei, B Sun… - Advanced Functional …, 2017 - Wiley Online Library
Alkyl chains are basic units in the design of organic semiconductors for purposes of
enhancing solubility, tuning electronic energy levels, and tailoring molecular packing. This …

Benzothiophene and benzosulfone fused pyrazino [2, 3-g] quinoxaline: Synthesis and semiconducting properties

F Ding, D Xia, X Ding, R Deng, C Ge, Y Yang… - Chinese Chemical …, 2023 - Elsevier
ABSTRACT A novel air-stable n-type benzothiaphene endcapped azaarene (BTPQ) and its
sulfonated derivative (BSPQ) were prepared via two pathways and characterized by NMR …

Triisopropylsilylethynyl-substituted indenofluorenes: carbonyl versus dicyanovinylene functionalization in one-dimensional molecular crystals and solution-processed …

R Ozdemir, S Park, İ Deneme, Y Park, Y Zorlu… - Organic Chemistry …, 2018 - pubs.rsc.org
The design and synthesis of novel electron-deficient and solution-processable polycyclic
aromatic hydrocarbons offers great opportunities for the development of low-cost and large …

Synthesis and Characterization of Two Unsymmetrical Indenofluorene Analogues: Benzo[5,6]-s-indaceno[1,2-b]thiophene and Benzo[5,6]-s-indaceno[2,1-b] …

JL Marshall, NJ O'Neal, LN Zakharov… - The Journal of Organic …, 2016 - ACS Publications
The synthesis and characterization of two benzo-indaceno-thiophene compounds (anti-BIT
and syn-BIT) are described. Two sequential Suzuki cross-couplings utilizing the halogen …

Indenone-fused N-heteroacenes

F Ding, D Xia, C Ge, Z Kang, Y Yang, R Fan… - Journal of Materials …, 2019 - pubs.rsc.org
The synthesis and optical, electronic and structural properties of indenone-fused azaacenes
are reported. With different fused lengths and units composed of azaacenes, the electronic …