Metal-catalyzed reductive coupling has emerged as an alternative to the use of
stoichiometric organometallic reagents in an increasingly diverse range of carbonyl and …

Allenes are the simplest class of cumulenes, with two contiguous C C bonds, and show
unique physical and chemical properties. These features make allenes particularly attractive …

Metal‐catalyzed reductive coupling reactions of aryl halides and (pseudo) halides with
carbonyl‐type compounds have undergone an impressive development within the last …

Since the pioneering work of Kharasch1 on the metalcatalyzed homocoupling reaction of
aromatic Grignard reagents (see 2) in the middle of the 20th century, cobaltcatalyzed carbon …

Tri-and tetrasubstituted olefins are widely present in biologically active molecules and
functional materials. However, the methods for the stereoselective construction of such …

A new regio-and stereoselective reductive coupling of alkynes and crotononitrile has been
developed via visible light organophotoredox cobalt dual catalysis. A variety of …

A Co-catalyzed highly regio-and enantioselective reductive coupling of alkynes and
aldehydes has been developed under visible light photoredox dual catalysis. A variety of …

Combinations of N-heterocyclic carbenes (NHCs) and fluoride salts of the iron-group metals
(Fe, Co, and Ni) have been shown to be excellent catalysts for the cross-coupling reactions …

A visible light‐induced Co‐catalyzed highly regio‐and stereoselective reductive coupling of
vinyl azaarenes and alkynes has been developed. Notably, Hünig's base together with …

Catalytic reductive coupling of enone, acrylate, or vinyl heteroaromatic pronucleophiles with
carbonyl or imine partners offers an alternative to base-mediated enolization in aldol-and …