Stabilization of an unprecedented hexanuclear secondary building unit in a thorium-based metal–organic framework
The crystal structures of thorium clusters are important for understanding the formation and
transformation mechanisms of actinide species in solution, which can in turns benefit …
transformation mechanisms of actinide species in solution, which can in turns benefit …
Plutonium oxide melt structure and covalency
Advances in nuclear power reactors include the use of mixed oxide fuel, containing uranium
and plutonium oxides. The high-temperature behaviour and structure of PuO2–x above …
and plutonium oxides. The high-temperature behaviour and structure of PuO2–x above …
Advances and perspectives of actinide chemistry from ex situ high pressure and high temperature chemical studies
High pressure high temperature (HP/HT) studies of actinide compounds allow the chemistry
and bonding of among the most exotic elements in the periodic table to be examined under …
and bonding of among the most exotic elements in the periodic table to be examined under …
An Azobenzene-Modified Photoresponsive Thorium–Organic Framework: Monitoring and Quantitative Analysis of Reversible trans–cis Photoisomerization
J Geng, K Liu, Y Liang, J Yu, K Hu, LH Yuan… - Inorganic …, 2021 - ACS Publications
Monitoring and quantification of the photoresponsive behavior of metal–organic frameworks
that respond to a light stimulus are crucial to establish a clear structure–activity relationship …
that respond to a light stimulus are crucial to establish a clear structure–activity relationship …
Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands
ZJ Li, S Guo, H Lu, Y Xu, Z Yue, L Weng… - Inorganic Chemistry …, 2020 - pubs.rsc.org
A simple binary synthetic approach with variable [HCOOH]/[Th (IV)] ratios and the addition of
water resulted in the self-assembly of six novel thorium formate complexes with well …
water resulted in the self-assembly of six novel thorium formate complexes with well …
Structural evolution from noninterpenetrated to interpenetrated thorium–organic frameworks exhibiting high propyne storage
YB Wu, C Xiong, QY Liu, JG Ma, F Luo… - Inorganic …, 2021 - ACS Publications
Two thorium–organic frameworks of [Th6O4 (OH) 4 (TFBPDC) 6 (H2O) 6] n (Th-TFBPDC)
and [Th6O4 (OH) 4 (TFBPDC) 4 (HCOO) 4 (H2O) 6] n (Th-TFBPDC-i) constructed from the 3 …
and [Th6O4 (OH) 4 (TFBPDC) 4 (HCOO) 4 (H2O) 6] n (Th-TFBPDC-i) constructed from the 3 …
Two Indium Sulfate Tellurites: Centrosymmetric In2(SO4)(TeO3)(OH)2(H2O) and Non-centrosymmetric In3(SO4)(TeO3)2F3(H2O)
YP Gong, YX Ma, SM Ying, JG Mao, F Kong - Inorganic Chemistry, 2019 - ACS Publications
Two new indium sulfate tellurites, namely, In2 (SO4)(TeO3)(OH) 2 (H2O) and In3
(SO4)(TeO3) 2F3 (H2O), were synthesized by hydrothermal method in a one-pot reaction …
(SO4)(TeO3) 2F3 (H2O), were synthesized by hydrothermal method in a one-pot reaction …
Electronic structure and properties of berkelium iodates
The reaction of 249Bk (OH) 4 with iodate under hydrothermal conditions results in the
formation of Bk (IO3) 3 as the major product with trace amounts of Bk (IO3) 4 also …
formation of Bk (IO3) 3 as the major product with trace amounts of Bk (IO3) 4 also …
Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks
Studying the coordination of actinide-based metal oxo clusters can provide valuable insights
for nuclear energy technologies and radioactive waste containment. Metal–organic …
for nuclear energy technologies and radioactive waste containment. Metal–organic …
A Tetravalent Plutonium Organic Framework Containing [Pu2O16] Dimers as Secondary Building Units: Synthesis, Structure, and Radiation Stability
Y Zhang, Y Du, L Li, Y Tao, K Li… - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary The second example of tetravalent plutonium carboxyl‐based
organic framework, 242Pu (OH)[PO [(C6H4) COO] 3]· H2O, termed as PuTPO (TPO= tris (4 …
organic framework, 242Pu (OH)[PO [(C6H4) COO] 3]· H2O, termed as PuTPO (TPO= tris (4 …