Microstructural and dynamical heterogeneities in ionic liquids
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …
molecular symmetry and charge delocalization. The versatility in combining varied cation …
Two-dimensional spectroscopy is being used to address core scientific questions in biology and materials science
Two-dimensional spectroscopy is a powerful tool for extracting structural and dynamic
information from a wide range of chemical systems. We provide a brief overview of the ways …
information from a wide range of chemical systems. We provide a brief overview of the ways …
Ionic liquids exhibit the piezoelectric effect
MI Hossain, GJ Blanchard - The Journal of Physical Chemistry …, 2023 - ACS Publications
The piezoelectric effect was discovered over a century ago, and it has found wide
application since that time. The direct piezoelectric effect is the production of charge upon …
application since that time. The direct piezoelectric effect is the production of charge upon …
Interfacial Speciation Determines Interfacial Chemistry: X‐ray‐Induced Lithium Fluoride Formation from Water‐in‐salt Electrolytes on Solid Surfaces
Abstract Super‐concentrated “water‐in‐salt” electrolytes recently spurred resurgent interest
for high energy density aqueous lithium‐ion batteries. Thermodynamic stabilization at high …
for high energy density aqueous lithium‐ion batteries. Thermodynamic stabilization at high …
Long-range interface effects in room temperature ionic liquids: vibrational lifetime studies of thin films
Interface effects in the room temperature ionic liquids (RTILs) 1-butyl-3-methylimidazolium
tetrafluoroborate (BmimBF4) and 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl) …
tetrafluoroborate (BmimBF4) and 1-butyl-3-methylimidazolium bis (trifluoromethylsulfonyl) …
Unraveling the Structure and Binding Energy of Adsorbed CO2/H2O on Amine Sorbents
DD Miller, J Yu, SSC Chuang - The Journal of Physical Chemistry …, 2020 - ACS Publications
One critical issue in the design of amine-based sorbents and solvents for next-generation
CO2 capture technology is the effect of H2O on the behavior of adsorbed CO2. To gain an …
CO2 capture technology is the effect of H2O on the behavior of adsorbed CO2. To gain an …
Copper-doped mesoporous silica supported dual acidic ionic liquid as an efficient and cooperative reusability catalyst for Biginelli reaction
N Yao, M Lu, XB Liu, J Tan, YL Hu - Journal of Molecular Liquids, 2018 - Elsevier
A series of MCM-41 supported functionalized ionic liquids doped with copper species were
prepared, characterized and evaluated as catalysts in the Biginelli reaction. Most of these …
prepared, characterized and evaluated as catalysts in the Biginelli reaction. Most of these …
Carbon Dioxide in a Supported Ionic Liquid Membrane: Structural and Rotational Dynamics Measured with 2D IR and Pump–Probe Experiments
Supported ionic liquid membranes (SILMs) are porous membranes impregnated with ionic
liquids (ILs) and used as advanced carbon capture materials. Here, two-dimensional …
liquids (ILs) and used as advanced carbon capture materials. Here, two-dimensional …
Controlling the dynamics of ionic liquid thin films via multilayer surface functionalization
The structural dynamics of planar thin films of an ionic liquid (IL) 1-butyl-3-
methylimidazolium bis (trifluoromethylsulfonyl) imide (BmimNTf2) as a function of surface …
methylimidazolium bis (trifluoromethylsulfonyl) imide (BmimNTf2) as a function of surface …
[HTML][HTML] Effects of pore size on water dynamics in mesoporous silica
Water confined in mesoporous silica plays a central role in its many uses ranging from gas
sorption to nanoconfined chemical reactions. Here, the influence of pore diameter (2.5–5.4 …
sorption to nanoconfined chemical reactions. Here, the influence of pore diameter (2.5–5.4 …