Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013 - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

When metal clusters meet carbon cages: endohedral clusterfullerenes

S Yang, T Wei, F Jin - Chemical society reviews, 2017 - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

Bonding inside and outside Fullerene Cages

L Bao, P Peng, X Lu - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Concrete crystallographic results of endohedral metallofullerenes (EMFs)
disclose that the bonding within the metallic clusters and the interactions between the metal …

Nanoscale fullerene compression of an yttrium carbide cluster

J Zhang, T Fuhrer, W Fu, J Ge… - Journal of the …, 2012 - ACS Publications
The nanoscale parameters of metal clusters and lattices have a crucial influence on the
macroscopic properties of materials. Herein, we provide a detailed study on the size and …

Carbon atoms trapped in cages: metal carbide clusterfullerenes

P Jin, C Tang, Z Chen - Coordination Chemistry Reviews, 2014 - Elsevier
Metal carbide clusterfullerenes (MCCFs), which trap two carbon atoms together with metal
atom (s) inside the fullerene cage, are a novel branch of endohedral metallofullerenes …

Clusters encapsulated in endohedral metallofullerenes: how strained are they?

Q Deng, AA Popov - Journal of the American Chemical Society, 2014 - ACS Publications
Endohedral clusters in metallofullerenes can vary in a broad range of geometrical
parameters following the size and shape of the host carbon cage. Obviously, distortions of …

[图书][B] Endohedral Metallofullerenes: Basics and Applications

X Lu, L Echegoyen, AL Balch, S Nagase, T Akasaka - 2014 - books.google.com
Knowledge on endohedral metallofullerenes (EMFs) has increased dramatically during the
last decade. Numerous research findings have been reported, making it an opportune time …

Crystallographic characterization of Er 2 C 2@ C 2 (43)-C 90, Er 2 C 2@ C 2 (40)-C 90, Er 2 C 2@ C 2 (44)-C 90, and Er 2 C 2@ C 1 (21)-C 90: the role of cage-shape …

S Hu, W Shen, P Zhao, T Xu, Z Slanina, M Ehara… - Nanoscale, 2019 - pubs.rsc.org
For endohedral metallofullerenes (EMFs), that is, fullerenes encapsulating metallic species,
cage size is known to be an important factor for cluster configuration adoption; however, the …

Endohedral fullerenes: the importance of electronic, size and shape complementarity between the carbon cages and the corresponding encapsulated clusters

MR Cerón, FF Li, LA Echegoyen - Journal of Physical Organic …, 2014 - Wiley Online Library
Cage‐cluster complementarity is of crucial importance in determining the sizes and
structures, as well as the properties of endohedral fullerenes. The encapsulated atoms or …

Theoretical prediction of new carbon allotropes

L Yang, HY He, BC Pan - The Journal of Chemical Physics, 2013 - pubs.aip.org
Novel carbon allotropes are predicted by optionally substituting carbon atoms in diamond
with carbon tetrahedrons. All these allotropes exhibit semiconducting properties, with …