Cu (I)-catalyzed click chemistry in glycoscience and their diverse applications
Copper (I)-catalyzed 1, 3-dipolar cycloaddition between organic azides and terminal
alkynes, commonly known as CuAAC or click chemistry, has been identified as one of the …
alkynes, commonly known as CuAAC or click chemistry, has been identified as one of the …
Recent progress in synthetic applications of hypervalent iodine (III) reagents
A Yoshimura, VV Zhdankin - Chemical Reviews, 2024 - ACS Publications
Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …
Catalyzing electrosynthesis: a homogeneous electrocatalytic approach to reaction discovery
Conspectus Electrochemistry has been used as a tool to drive chemical reactions for over
two centuries. With the help of an electrode and a power source, chemists are bestowed with …
two centuries. With the help of an electrode and a power source, chemists are bestowed with …
Energy transfer-enabled unsymmetrical diamination using bifunctional nitrogen-radical precursors
G Tan, M Das, R Kleinmans, F Katzenburg… - Nature Catalysis, 2022 - nature.com
Vicinal diamines, especially unsymmetrical ones, are among the most common structural
motifs in biologically active molecules, natural products and pharmaceuticals. While the …
motifs in biologically active molecules, natural products and pharmaceuticals. While the …
The persistent radical effect in organic synthesis
Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …
selective cross‐coupling of two different radicals is challenging and not a synthetically …
Cu-electrocatalytic diazidation of alkenes at ppm catalyst loading
CY Cai, YT Zheng, JF Li, HC Xu - Journal of the American …, 2022 - ACS Publications
The 1, 2-diamine motif is prevalent in natural products, small-molecule pharmaceuticals, and
catalysts for asymmetric synthesis. Transition metal catalyzed alkene diazidation has …
catalysts for asymmetric synthesis. Transition metal catalyzed alkene diazidation has …
Metal-catalyzed electrochemical diazidation of alkenes
Vicinal diamines are a common structural motif in bioactive natural products, therapeutic
agents, and molecular catalysts, motivating the continuing development of efficient …
agents, and molecular catalysts, motivating the continuing development of efficient …
An electrocatalytic approach to the radical difunctionalization of alkenes
Given its many distinct characteristics, electrochemistry represents an attractive approach to
meet the prevailing trends in organic synthesis. In particular, electrocatalysis—a process that …
meet the prevailing trends in organic synthesis. In particular, electrocatalysis—a process that …
Photochemical diazidation of alkenes enabled by ligand-to-metal charge transfer and radical ligand transfer
Vicinal diamines are privileged synthetic motifs in chemistry due to their prevalence and
powerful applications in bioactive molecules, pharmaceuticals, and ligand design for …
powerful applications in bioactive molecules, pharmaceuticals, and ligand design for …
New strategies for the synthesis of aliphatic azides
P Sivaguru, Y Ning, X Bi - Chemical Reviews, 2021 - ACS Publications
Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …
pharmaceuticals. These compounds are also recognized as useful precursors for the …