Cu (I)-catalyzed click chemistry in glycoscience and their diverse applications

AK Agrahari, P Bose, MK Jaiswal, S Rajkhowa… - Chemical …, 2021 - ACS Publications
Copper (I)-catalyzed 1, 3-dipolar cycloaddition between organic azides and terminal
alkynes, commonly known as CuAAC or click chemistry, has been identified as one of the …

Recent progress in synthetic applications of hypervalent iodine (III) reagents

A Yoshimura, VV Zhdankin - Chemical Reviews, 2024 - ACS Publications
Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Catalyzing electrosynthesis: a homogeneous electrocatalytic approach to reaction discovery

JC Siu, N Fu, S Lin - Accounts of chemical research, 2020 - ACS Publications
Conspectus Electrochemistry has been used as a tool to drive chemical reactions for over
two centuries. With the help of an electrode and a power source, chemists are bestowed with …

Energy transfer-enabled unsymmetrical diamination using bifunctional nitrogen-radical precursors

G Tan, M Das, R Kleinmans, F Katzenburg… - Nature Catalysis, 2022 - nature.com
Vicinal diamines, especially unsymmetrical ones, are among the most common structural
motifs in biologically active molecules, natural products and pharmaceuticals. While the …

The persistent radical effect in organic synthesis

D Leifert, A Studer - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Cu-electrocatalytic diazidation of alkenes at ppm catalyst loading

CY Cai, YT Zheng, JF Li, HC Xu - Journal of the American …, 2022 - ACS Publications
The 1, 2-diamine motif is prevalent in natural products, small-molecule pharmaceuticals, and
catalysts for asymmetric synthesis. Transition metal catalyzed alkene diazidation has …

Metal-catalyzed electrochemical diazidation of alkenes

N Fu, GS Sauer, A Saha, A Loo, S Lin - Science, 2017 - science.org
Vicinal diamines are a common structural motif in bioactive natural products, therapeutic
agents, and molecular catalysts, motivating the continuing development of efficient …

An electrocatalytic approach to the radical difunctionalization of alkenes

GS Sauer, S Lin - ACS Catalysis, 2018 - ACS Publications
Given its many distinct characteristics, electrochemistry represents an attractive approach to
meet the prevailing trends in organic synthesis. In particular, electrocatalysis—a process that …

Photochemical diazidation of alkenes enabled by ligand-to-metal charge transfer and radical ligand transfer

KJ Bian, SC Kao, D Nemoto Jr, XW Chen… - Nature …, 2022 - nature.com
Vicinal diamines are privileged synthetic motifs in chemistry due to their prevalence and
powerful applications in bioactive molecules, pharmaceuticals, and ligand design for …

New strategies for the synthesis of aliphatic azides

P Sivaguru, Y Ning, X Bi - Chemical Reviews, 2021 - ACS Publications
Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …