Electrostatic interactions within mixed-valent compounds

A Hildebrandt, D Miesel, H Lang - Coordination Chemistry Reviews, 2018 - Elsevier
The electrochemical properties of bi-and multi-metallic compounds are a convolution of
several factors, among which through-bond electron transfer and through-space electrostatic …

Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles

D Miesel, A Hildebrandt, H Lang - Current Opinion in Electrochemistry, 2018 - Elsevier
Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles -
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A Dibenzotetrathiafulvalene-Bridged Bis (alkenylruthenium) Complex and Its One-and Two-Electron-Oxidized Forms

FS Gogesch, LS Laininger, N Sokov… - Inorganic …, 2023 - ACS Publications
We report on the synthesis of the new bis (alkenylruthenium) complex DBTTF-(ViRu) 2 with
a longitudinally extended, π-conjugated dibenzotetrathiafulvalene (DBTTF) bridge …

Diruthenium Complexes with π-Extended Bridging Bis (alkenyl) arylene Ligands, A Derived Metallamacrocycle, and Their Oxidized Forms

FS Gogesch, S Schwab, A Rehse, M Linseis… - …, 2023 - ACS Publications
We report on dinuclear alkenylruthenium complexes with π-extended trans, trans-
distyrylbenzene (1-V) or 1, 4-(2-phenylethynyl) benzene (1-A) linkers akin to …

Rational Control of Conformational Distributions and Mixed‐Valence Characteristics in Diruthenium Complexes

JBG Gluyas, S Gückel, M Kaupp… - Chemistry–A European …, 2016 - Wiley Online Library
The electronic characteristics of mixed‐valence complexes are often inferred from the shape
of the inter‐valence charge transfer (IVCT) band, which usually falls in the near infrared …

1, 4-Divinylphenylene-bridged diruthenium complexes with 2-hydroxypyridine-and 2-or 8-hydroxyquinoline-olate ligands

OS Abdel-Rahman, M Linseis, A Alowais… - … für Naturforschung B, 2023 - degruyter.com
Four divinylphenylene-bridged diruthenium complexes [{Ru (CO)(P i Pr3) 2 (L-κ 2 [N, O]–)} 2
(μ-CH= CH-C6H4-CH= CH-1, 4)](2a–2d) with N, O-chelating 2-hydroxypyridine and 2 …

Electron‐Rich Diruthenium Complexes with π‐Extended Alkenyl Ligands and Their F4TCNQ Charge‐Transfer Salts**

R Das, M Linseis, SM Schupp… - … A European Journal, 2022 - Wiley Online Library
The synthesis of dinuclear ruthenium alkenyl complexes with {Ru (CO)(PiPr3) 2 (L)} entities
(L= Cl− in complexes Ru2‐3 and Ru2‐7; L= acetylacetonate (acac−) in complexes Ru2‐4 …

[HTML][HTML] Pyrene fluorescence in 2, 7-di (4-phenylethynyl) pyrene-bridged bis (alkenylruthenium) complexes

FS Gogesch, L Bauer, FD Vollstädt, M Linseis… - Dalton …, 2024 - pubs.rsc.org
Complexes PyrDPE-RuCl and PyrDPE-Ruacac with a π-extended 2, 7-di (4-phenylethynyl)
pyrene linker undergo simultaneous one-electron oxidations of their {Ru}-styryl entities. The …

Influence of quinoidal distortion on the electronic properties of oxidized divinylarylene-bridged diruthenium complexes

N Rotthowe, J Zwicker, RF Winter - Organometallics, 2019 - ACS Publications
We present four new divinylarylene-bridged diruthenium complexes of the type {Ru (CO) Cl
(P i Pr3) 2} 2 (μ-CH═ CH–Ar–CH═ CH) with naphthalene-1, 4-diyl (Ru 2 NA), 2, 1, 3 …

Redox‐Active Tetraruthenium Macrocycles Built from 1, 4‐Divinylphenylene‐Bridged Diruthenium Complexes

S Scheerer, M Linseis, E Wuttke… - … A European Journal, 2016 - Wiley Online Library
Metallamacrocylic tetraruthenium complexes were generated by treatment of 1, 4‐
divinylphenylene‐bridged diruthenium complexes with functionalized 1, 3‐benzene …