Mechanical properties and peculiarities of molecular crystals

WM Awad, DW Davies, D Kitagawa… - Chemical Society …, 2023 - pubs.rsc.org
In the last century, molecular crystals functioned predominantly as a means for determining
the molecular structures via X-ray diffraction, albeit as the century came to a close the …

Design of collective motions from synthetic molecular switches, rotors, and motors

D Dattler, G Fuks, J Heiser, E Moulin, A Perrot… - Chemical …, 2019 - ACS Publications
Precise control over molecular movement is of fundamental and practical importance in
physics, biology, and chemistry. At nanoscale, the peculiar functioning principles and the …

The rise of the dynamic crystals

P Naumov, DP Karothu, E Ahmed… - Journal of the …, 2020 - ACS Publications
The anticipated shift in the focal point of interest of solid-state chemists, crystal engineers,
and crystallographers from structure to properties to function parallels the need to apply our …

Mechanically responsive molecular crystals

P Naumov, S Chizhik, MK Panda, NK Nath… - Chemical …, 2015 - ACS Publications
Transformation of energy into motion (work) is one of the basic processes of energy
conversion in nature. The processes of actuation underlying the transduction of light …

[HTML][HTML] Photo-actuators via epitaxial growth of microcrystal arrays in polymer membranes

W Xu, DM Sanchez, U Raucci, H Zhou, X Dong, M Hu… - Nature Materials, 2023 - nature.com
Photomechanical crystals composed of three-dimensionally ordered and densely packed
photochromes hold promise for high-performance photochemical actuators. However, bulk …

Performance of molecular crystals in conversion of light to mechanical work

J Mahmoud Halabi, E Ahmed… - Proceedings of the …, 2021 - National Acad Sciences
Dynamic molecular crystals have recently received ample attention as an emerging class of
energy-transducing materials, yet have fallen short of developing into fully realized …

Control of photomechanical crystal twisting by illumination direction

D Kitagawa, H Tsujioka, F Tong, X Dong… - Journal of the …, 2018 - ACS Publications
Photomechanical molecular crystals have been investigated as mesoscopic photoactuators.
Here, we report how the photomechanical twisting of 1, 2-bis (2-methyl-5-phenyl-3-thienyl) …

An elastic organic crystal enables macroscopic photoinduced crystal elongation

YS Chen, CH Wang, YH Hu, CYD Lu… - Journal of the American …, 2023 - ACS Publications
Among the various types of photomechanical deformations of organic crystals, photoinduced
elongation of millimeter-scale crystals has yet to be demonstrated. Here we report that the …

Polymorph-derived diversification of crystal actuation by photoisomerization and the photothermal effect

S Hasebe, Y Hagiwara, K Takechi… - Chemistry of …, 2022 - ACS Publications
Mechanically responsive materials have been investigated extensively over the past two
decades. Diversification of actuation modes is essential for the practical application of …

Photothermally driven high-speed crystal actuation and its simulation

S Hasebe, Y Hagiwara, J Komiya, M Ryu… - Journal of the …, 2021 - ACS Publications
Mechanically responsive crystals have been increasingly explored, mainly based on
photoisomerization. However, photoisomerization has some disadvantages for crystal …