Sources of Nitrogen-, Sulfur-, and Phosphorus-containing feedstocks for prebiotic chemistry in the planetary environment
ZR Todd - Life, 2022 - mdpi.com
Biochemistry on Earth makes use of the key elements carbon, hydrogen, oxygen, nitrogen,
phosphorus, and sulfur (or CHONPS). Chemically accessible molecules containing these …
phosphorus, and sulfur (or CHONPS). Chemically accessible molecules containing these …
Formation of phosphorus monoxide (PO) in the interstellar medium: Insights from quantum-chemical and kinetic calculations
JG de la Concepción, C Puzzarini… - The Astrophysical …, 2021 - iopscience.iop.org
In recent years, phosphorus monoxide (PO), an important molecule for prebiotic chemistry,
has been detected in star-forming regions and in the comet 67P/Churyumov-Gerasimenko …
has been detected in star-forming regions and in the comet 67P/Churyumov-Gerasimenko …
Reaction dynamics of P(S) O(X) O(P) PO(X) on a global CHIPR potential energy surface of PO(XA): implications for atmospheric …
G Chen, Z Qin, X Li, L Liu - Atmospheric Chemistry and Physics, 2023 - acp.copernicus.org
The reaction dynamics of P (4 S)+ O 2 (X 3 Σ g-)→ O (3 P)+ PO (X 2 Π) are thought to be
important in atmospheric and interstellar chemistry. Based on the state-of-the-art ab initio …
important in atmospheric and interstellar chemistry. Based on the state-of-the-art ab initio …
Phosphine reactivity and its implications for pyrolysis experiments and astrochemistry
L Baptista, AA De Almeida - The Journal of Physical Chemistry A, 2023 - ACS Publications
Despite the importance of phosphorus-bearing molecules for life and their abundance
outside Earth, the chemistry of those compounds still is poorly described. The present study …
outside Earth, the chemistry of those compounds still is poorly described. The present study …
Experimental study of the removal of excited state phosphorus atoms by H2O and H2: implications for the formation of PO in stellar winds
KM Douglas, D Gobrecht… - Monthly Notices of the …, 2022 - academic.oup.com
The reactions of the low-lying metastable states of atomic phosphorus, P (2D) and P (2P),
with H2O and H2 were studied by the pulsed laser photolysis at 248 nm of PCl3, combined …
with H2O and H2 were studied by the pulsed laser photolysis at 248 nm of PCl3, combined …
Relevance of the P+ O2 Reaction for PO Formation in Astrochemical Environments: Electronic Structure Calculations and Kinetic Simulations
JG de la Concepción, C Cavallotti… - The Astrophysical …, 2024 - iopscience.iop.org
Phosphorus monoxide (PO) is a key brick of prebiotic chemistry since it is a potential
precursor of phosphates, which are present in all living systems. Prompted by the lack of …
precursor of phosphates, which are present in all living systems. Prompted by the lack of …
Phosphorus chemistry in the Earth's upper atmosphere
The ablation of phosphorus from interplanetary dust particles entering the Earth's
atmosphere is a potentially significant source of this key bioelement. In this study, the …
atmosphere is a potentially significant source of this key bioelement. In this study, the …
[HTML][HTML] Injection of meteoric phosphorus into planetary atmospheres
JD Carrillo-Sánchez, DL Bones, KM Douglas… - Planetary and Space …, 2020 - Elsevier
This study explores the delivery of phosphorus to the upper atmospheres of Earth, Mars, and
Venus via the ablation of cosmic dust particles. Micron-size meteoritic particles were flash …
Venus via the ablation of cosmic dust particles. Micron-size meteoritic particles were flash …
Kinetic Study of the Reactions PO + O2 and PO2 + O3 and Spectroscopy of the PO Radical
KM Douglas, MA Blitz, TP Mangan… - The Journal of …, 2020 - ACS Publications
The kinetics of the reactions of PO with O2 and PO2 with O3 were studied at temperatures
ranging from∼ 190 to 340 K, using a pulsed laser photolysis-laser induced fluorescence …
ranging from∼ 190 to 340 K, using a pulsed laser photolysis-laser induced fluorescence …
Microcanonical tunneling rates from density-of-states instanton theory
Semiclassical instanton theory is a form of quantum transition-state theory which can be
applied to the computation of thermal reaction rates in complex molecular systems including …
applied to the computation of thermal reaction rates in complex molecular systems including …