Sources of Nitrogen-, Sulfur-, and Phosphorus-containing feedstocks for prebiotic chemistry in the planetary environment

ZR Todd - Life, 2022 - mdpi.com
Biochemistry on Earth makes use of the key elements carbon, hydrogen, oxygen, nitrogen,
phosphorus, and sulfur (or CHONPS). Chemically accessible molecules containing these …

Formation of phosphorus monoxide (PO) in the interstellar medium: Insights from quantum-chemical and kinetic calculations

JG de la Concepción, C Puzzarini… - The Astrophysical …, 2021 - iopscience.iop.org
In recent years, phosphorus monoxide (PO), an important molecule for prebiotic chemistry,
has been detected in star-forming regions and in the comet 67P/Churyumov-Gerasimenko …

Reaction dynamics of P(S)  O(X)  O(P)  PO(X) on a global CHIPR potential energy surface of PO(XA): implications for atmospheric …

G Chen, Z Qin, X Li, L Liu - Atmospheric Chemistry and Physics, 2023 - acp.copernicus.org
The reaction dynamics of P (4 S)+ O 2 (X 3 Σ g-)→ O (3 P)+ PO (X 2 Π) are thought to be
important in atmospheric and interstellar chemistry. Based on the state-of-the-art ab initio …

Phosphine reactivity and its implications for pyrolysis experiments and astrochemistry

L Baptista, AA De Almeida - The Journal of Physical Chemistry A, 2023 - ACS Publications
Despite the importance of phosphorus-bearing molecules for life and their abundance
outside Earth, the chemistry of those compounds still is poorly described. The present study …

Experimental study of the removal of excited state phosphorus atoms by H2O and H2: implications for the formation of PO in stellar winds

KM Douglas, D Gobrecht… - Monthly Notices of the …, 2022 - academic.oup.com
The reactions of the low-lying metastable states of atomic phosphorus, P (2D) and P (2P),
with H2O and H2 were studied by the pulsed laser photolysis at 248 nm of PCl3, combined …

Relevance of the P+ O2 Reaction for PO Formation in Astrochemical Environments: Electronic Structure Calculations and Kinetic Simulations

JG de la Concepción, C Cavallotti… - The Astrophysical …, 2024 - iopscience.iop.org
Phosphorus monoxide (PO) is a key brick of prebiotic chemistry since it is a potential
precursor of phosphates, which are present in all living systems. Prompted by the lack of …

Phosphorus chemistry in the Earth's upper atmosphere

JMC Plane, W Feng, KM Douglas - Journal of Geophysical …, 2021 - Wiley Online Library
The ablation of phosphorus from interplanetary dust particles entering the Earth's
atmosphere is a potentially significant source of this key bioelement. In this study, the …

[HTML][HTML] Injection of meteoric phosphorus into planetary atmospheres

JD Carrillo-Sánchez, DL Bones, KM Douglas… - Planetary and Space …, 2020 - Elsevier
This study explores the delivery of phosphorus to the upper atmospheres of Earth, Mars, and
Venus via the ablation of cosmic dust particles. Micron-size meteoritic particles were flash …

Kinetic Study of the Reactions PO + O2 and PO2 + O3 and Spectroscopy of the PO Radical

KM Douglas, MA Blitz, TP Mangan… - The Journal of …, 2020 - ACS Publications
The kinetics of the reactions of PO with O2 and PO2 with O3 were studied at temperatures
ranging from∼ 190 to 340 K, using a pulsed laser photolysis-laser induced fluorescence …

Microcanonical tunneling rates from density-of-states instanton theory

W Fang, P Winter, JO Richardson - Journal of Chemical Theory …, 2020 - ACS Publications
Semiclassical instanton theory is a form of quantum transition-state theory which can be
applied to the computation of thermal reaction rates in complex molecular systems including …