Dearomatization strategies in a multicomponent fashion often result in complex heterocyclic
frameworks, which have attracted the attention of chemists due to their natural product-like …

An important strategy for the efficient generation of diversity in molecular structures is the
utilization of common starting materials in chemodivergent transformations. The most …

A combination of NHC organocatalysis and transition-metal catalysis gives rise to
fundamentally new cooperative reactivity and enables the regio-and enantioselective …

The development of switchable chemo-, regio-, or diastereodivergent reactions, in which two
or more structurally and stereogenically different types of chiral products could be produced …

The highly enantioselective [5+ 2] annulation of enals with vinylethylene carbonates through
a cooperative N-heterocyclic carbene (NHC)/Pd catalytic system is reported. The use of a …

Regulating both the chemo‐and diastereoselectivity, divergently, of a reaction is highly
attractive but extremely challenging. Presented herein is a catalyst‐controlled switch in the …

A comprehensive investigation of the mechanism of the highly enantioselective Pd (PPh3)
4/NHC-catalyzed annulation of vinyl benzoxazinanones and enals has been conducted. A …

A cooperative N-heterocyclic carbene (NHC)/iridium catalysis has been developed to
achieve highly stereoselective and regiodivergent [3+ 2] and [3+ 3] annulation reactions of 2 …

The recent advances in the N‐heterocyclic carbene (NHC)‐organocatalyzed generation of
azolium enolate intermediates and their subsequent interception with electrophiles are …

Cooperative dual catalysis is a powerful strategy for achieving unique reactivity by
combining catalysts with orthogonal modes of action. This approach allows for independent …