Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …
(SMMs), as any future potential application in this class of molecules is directly correlated to …
Single-electron lanthanide-lanthanide bonds inside fullerenes toward robust redox-active molecular magnets
Conspectus A characteristic phenomenon of lanthanide–fullerene interactions is the transfer
of metal valence electrons to the carbon cage. With early lanthanides such as La, a …
of metal valence electrons to the carbon cage. With early lanthanides such as La, a …
The second quantum revolution: role and challenges of molecular chemistry
Implementation of modern Quantum Technologies might benefit from the remarkable
quantum properties shown by molecular spin systems. In this Perspective, we highlight the …
quantum properties shown by molecular spin systems. In this Perspective, we highlight the …
Embedded nano spin sensor for in situ probing of gas adsorption inside porous organic frameworks
J Zhang, L Liu, C Zheng, W Li, C Wang… - nature …, 2023 - nature.com
Spin-based sensors have attracted considerable attention owing to their high sensitivities.
Herein, we developed a metallofullerene-based nano spin sensor to probe gas adsorption …
Herein, we developed a metallofullerene-based nano spin sensor to probe gas adsorption …
Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond
Engineering intramolecular exchange interactions between magnetic metal atoms is a
ubiquitous strategy for designing molecular magnets. For lanthanides, the localized nature …
ubiquitous strategy for designing molecular magnets. For lanthanides, the localized nature …
Origin of the anomalously low Raman exponents in single molecule magnets
The Raman exponent of single molecular magnetic relaxation may take various unexpected
values because of rich phonon spectra and spin-phonon coupling of molecular crystals. We …
values because of rich phonon spectra and spin-phonon coupling of molecular crystals. We …
High-temperature magnetic blocking in a monometallic dysprosium azafullerene single-molecule magnet
Single-molecule magnets (SMMs) showing magnetic blocking near or above liquid nitrogen
temperature have recently been achieved by inducing exceptionally strong and axial crystal …
temperature have recently been achieved by inducing exceptionally strong and axial crystal …
Steering Single-Electron Metal–Metal Bonds and Hyperfine Coupling between a Transition Metal-Lanthanide Heteronuclear Bimetal Confined in Carbon Cages
W Xiang, Z Hu, J Xin, H Jin, Z Jiang, X Han… - Journal of the …, 2023 - ACS Publications
Metal complexes bearing single-electron metal–metal bonds (SEMBs) exhibit unusual
electronic structures evoking strong magnetic coupling, and such bonds can be stabilized in …
electronic structures evoking strong magnetic coupling, and such bonds can be stabilized in …
Actinide-lanthanide single electron metal-metal bond formed in mixed-valence di-metallofullerenes
Understanding metal-metal bonding involving f-block elements has been a challenging goal
in chemistry. Here we report a series of mixed-valence di-metallofullerenes, ThDy@ C2 n (2 …
in chemistry. Here we report a series of mixed-valence di-metallofullerenes, ThDy@ C2 n (2 …
External stimuli modulate the magnetic relaxation of lanthanide single-molecule magnets
Z Zhu, XL Li, S Liu, J Tang - Inorganic Chemistry Frontiers, 2020 - pubs.rsc.org
Mutilfunctional molecular magnetic materials have promising potential for use as future
molecular devices, such as for magneto-luminescence sensing, optical switching …
molecular devices, such as for magneto-luminescence sensing, optical switching …