Recent advances in subphthalocyanines and related subporphyrinoids

G Lavarda, J Labella, MV Martínez-Díaz… - Chemical Society …, 2022 - pubs.rsc.org
Half a century after the synthesis of the first subporphyrinoid, the study of tripyrrole and
trisoindole porphyrin analogues constitutes a fervent and rapidly expanding research area …

Synthetic chlorins, possible surrogates for chlorophylls, prepared by derivatization of porphyrins

M Taniguchi, JS Lindsey - Chemical reviews, 2017 - ACS Publications
Chlorophylls make Earth green, are the central constituents in the engine of photosynthesis,
and not surprisingly have garnered immense attention. A chlorin, the core chromophore of a …

Subphthalocyanines, subporphyrazines, and subporphyrins: Singular nonplanar aromatic systems

CG Claessens, D Gonzalez-Rodriguez… - Chemical …, 2014 - ACS Publications
1. INTRODUCTION Porphyrins (Ps) 1, 2 and their best known synthetic analogues, the
phthalocyanines (Pcs; 2− 10 Chart 1) represent one of the most widely studied macrocyclic …

Recent advances in subporphyrins and triphyrin analogues: contracted porphyrins comprising three pyrrole rings

S Shimizu - Chemical Reviews, 2017 - ACS Publications
Subporphyrinato boron (subporphyrin) was elusive until the syntheses of
tribenzosubporphine in 2006 and meso-aryl-substituted subporphyrin in 2007. These novel …

B (III)-subporphyrazines, B (III)-subporphyrins and their hybrids

Z Li, Q Gong, E Hao, L Jiao - Coordination Chemistry Reviews, 2023 - Elsevier
In recent years, subporphyrazines and subporphyrins, as a class of fascinating ring-
contracted porphyrinoids containing boron, have been widely developed as the promising …

Selective electrochemical oxygenation of alkylarenes to carbonyls

X Li, F Bai, C Liu, X Ma, C Gu, B Dai - Organic Letters, 2021 - ACS Publications
An efficient electrochemical method for benzylic C (sp3)–H bond oxidation has been
developed. A variety of methylarenes, methylheteroarenes, and benzylic (hetero) …

Synthesis of Subporphyrin Free Bases

L Liu, J Kim, L Xu, Y Rao, M Zhou, B Yin… - Angewandte …, 2022 - Wiley Online Library
BIII subporphyrins are the legitimate ring‐contracted porphyrins consisting of three pyrroles
and three meso‐carbons and their chemistry has been extensively developed since the first …

Visible light-driven water oxidation with a subporphyrin sensitizer and a water oxidation catalyst

M Yamamoto, Y Nishizawa, P Chábera, F Li… - Chemical …, 2016 - pubs.rsc.org
A new subporphyrin was synthesized for use as a molecular sensitizer in electrochemical
and dye-sensitized photoelectrochemical water oxidation. A photoelectrochemical cell with a …

Subporphyrins: a legitimate ring-contracted porphyrin with versatile electronic and optical properties

A Osuka, E Tsurumaki, T Tanaka - Bulletin of the Chemical …, 2011 - academic.oup.com
After a brief survey of our efforts in the development of novel porphyrinoids that include
meso–meso-linked porphyrin arrays, meso-aryl expanded porphyrins, and transition-metal …

Subporphyrins: emerging contracted porphyrins with aromatic 14π-electronic systems and bowl-shaped structures: rational and unexpected synthetic routes

Y Inokuma, A Osuka - Dalton Transactions, 2008 - pubs.rsc.org
Subporphyrin is a ring-contracted porphyrin congener consisting of three pyrrolic subunits
domed in a C3 symmetric bowl arrangement. Subporphyrin had long been elusive until the …