Deoxy sugars exist in numerous bioactive molecules and exert significant influences on their
physical, chemical, and biological properties. Due to the absence of directing group at C-2 …

Pd‐catalyzed stereoselective glycosylations using unsaturated sugar derivatives, glycals,
have been successfully achieved in recent years. This review focuses on approaches to …

L‐Prolinethioamide catalyzes direct stereoselective glycosylation of glycal donors to access
2‐deoxyglycosides under moderate reaction conditions. This proposed glycosylation …

Bi (OTf) 3 promoted direct and highly stereoselective glycosylation of “disarmed” and
“armed” glycals to synthesize 2-deoxyglycosides has been reported. The tunable and …

We herein reveal the possibility of the C-4 neighboring group/remote group participation
(NGP/RGP) facilitating the stabilization of the anomeric center via dioxolenium intermediates …

This letter describes the development of an α-selective glycosylation using l-oleandrose, a 2-
deoxysugar that is frequently found in natural products, and its application to the total …

The development of catalytic systems with different chemo-and biocatalytic functionalities for
sustainable one-pot multistep transformations represents a big challenge in modern …

Dideoxy sugars constitute an important class of anticancer antibiotics natural products and
serve as essential medicinal tools for carbohydrate-based drug discovery and vaccine …

The synthesis of 2‐C‐glycals and 2‐C‐ribals was achieved in good yields using a nickel‐
catalyzed cross‐coupling between 2‐iodoglycals and 2‐iodoribal respectively and Grignard …

2-Deoxy glycosyl ortho-[1-(p-MeOPhenyl) Vinyl] Benzoates (PMPVB) have been presented
as stable, reactive glycosyl donors for the synthesis of 2-deoxy α-glycosides. The donors …