Acid catalysis by heteropoly acids

MN Timofeeva - Applied Catalysis A: General, 2003 - Elsevier
The achievements in the field of acid catalysis by heteropoly acids having different structures
HxPW11LO40 (L= ZrIV, TiIV, ThIV), HxZW12O40 (Z= SiIV, PV, BIII, CoIII, GeIV) …

Esterification of oleic acid with ethanol by 12-tungstophosphoric acid supported on zirconia

CF Oliveira, LM Dezaneti, FAC Garcia… - Applied Catalysis A …, 2010 - Elsevier
Esterification of organic acids with alcohols produces an industrially important class of
substances with a variety of applications. This work presents an impregnation route to …

[图书][B] Metal-oxygen clusters: the surface and catalytic properties of heteropoly oxometalates

JB Moffat - 2001 - books.google.com
Metal-Oxygen Clusters is the first book, providing an overview of the surface chemistry and
catalytic properties of heteropoly oxometalates. After a brief look at the early knowledge of …

Gas conversion to liquid fuels and chemicals: The methanol route‐catalysis and processes development

T Mokrani, M Scurrell - Catalysis Reviews, 2009 - Taylor & Francis
Natural gas is acknowledged as the fuel for the 21st century. Natural gas is the cleanest
fossil fuel, and it is abundant. Furthermore, it is dispersed over a wide region, as opposite to …

Acidic Cs+, NH4+, and K+ salts of 12-tungstophosphoric acid as solid catalysts for isobutane/2-butene alkylation

A Corma, A Martınez, C Martınez - Journal of Catalysis, 1996 - Elsevier
The caesium, ammonium, and potassium salts of 12-tungstophosphoric acid (HPW) have
been prepared with different stoichiometries (1≤ x≤ 3), and their catalytic behavior …

Cation Effects on the Brønsted Acidity of Solid Tungstosilicic Acid Clusters

G Cai, P Deshlahra, YHC Chin - ACS Catalysis, 2024 - ACS Publications
Rigorous kinetic assessments, pyridine chemical titration and desorption, together with
density functional theory calculations establish the trends in the modulation of chemical …

Elucidation of the mechanism of dehydration of methanol over 12-tungstophosphoric acid using infrared photoacoustic spectroscopy

JG Highfield, JB Moffat - Journal of Catalysis, 1985 - Elsevier
Abstract Photoacoustic Fourier-Transform Infrared Spectroscopy (PAS-FTIR) has been used
to study the interaction of CH 3 OH with 12-tungstophosphoric acid (H 3 PW 12 O 40) and …

Acid-redox properties of titania-supported 12-molybdophosphates for methanol oxidation

S Damyanova, ML Cubeiro, JLG Fierro - Journal of Molecular Catalysis A …, 1999 - Elsevier
Physicochemical and catalytic properties of titania-supported 12-molybdophosphates have
been investigated. The samples were characterized by the S (BET) method, Fourier …

Implicit and explicit microporosity in heteropoly oxometalates

JB Moffat - Journal of molecular catalysis, 1989 - Elsevier
Nonporous heteropoly oxometalates are shown to be capable of absorbing polar molecules
into their bulk structures while retaining their properties as solids. The results from …

A microcalorimetric investigation of heteropolyacids

LC Jozefowicz, HG Karge, E Vasilyeva, JB Moffat - Microporous Materials, 1993 - Elsevier
Differential heats of ammonia sorption onto and into heteropolyacids (HPA's) of tungsten
and molybdenum (HPW, HSiW, HPMo and HSiMo) were measured microcalorimetrically to …